Electronically deficient (R-ax,S,S)-F-12-C-3-TunePhos and its applications in asymmetric 1,4-addition reactions

doi:10.1016/j.tetlet.2016.03.072

	Electronically deficient (R-ax,S,S)-F-12-C-3-TunePhos and its applications in asymmetric 1,4-addition reactions
	Hu, Shu-Bo; Zhou, Ji; Zhou, Yong-Gui; Chen, Zhang-Pei
刊名	TETRAHEDRON LETTERS
	2016-04-27
卷号	57 期号:17 页码:1925-1929
关键词	Fluorinated Diphosphine Ligand Rhodium 1 4-addition Reactions
ISSN号	0040-4039
DOI	10.1016/j.tetlet.2016.03.072
文献子类	Article
英文摘要	A novel electronically deficient chiral diphosphine ligand (R-ax,S,S)-F-12-C-3-TunePhos has been concisely synthesized. The electron-poor ligand features both chiral centers and chiral axis bearing fluoro-functional groups on each phosphorus phenyl ring based on C-3-TunePhos backbone. The catalyst composed of this ligand and rhodium showed excellent activities and enantioselectivities in asymmetric 1,4-addition reactions of arylboronic acids to diverse alpha,beta-unsaturated ketones with up to 99% ee. (C) 2016 Elsevier Ltd. All rights reserved.
WOS关键词	CHIRAL DIPHOSPHINE LIGANDS ; CATALYZED STEREOSELECTIVE REACTIONS ; ENANTIOSELECTIVE HYDROGENATION ; ARYLBORONIC ACIDS ; ORGANOBORONIC ACIDS ; CONJUGATE ADDITION ; OLEFIN LIGANDS ; ALPHA,BETA-UNSATURATED KETONES ; PHOSPHORUS LIGANDS ; MEOBIPHEP ANALOGS
WOS研究方向	Chemistry
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000374601000025
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170774]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zhou, Yong-Gui
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Hu, Shu-Bo,Zhou, Ji,Zhou, Yong-Gui,et al. Electronically deficient (R-ax,S,S)-F-12-C-3-TunePhos and its applications in asymmetric 1,4-addition reactions[J]. TETRAHEDRON LETTERS,2016,57(17):1925-1929.
APA	Hu, Shu-Bo,Zhou, Ji,Zhou, Yong-Gui,&Chen, Zhang-Pei.(2016).Electronically deficient (R-ax,S,S)-F-12-C-3-TunePhos and its applications in asymmetric 1,4-addition reactions.TETRAHEDRON LETTERS,57(17),1925-1929.
MLA	Hu, Shu-Bo,et al."Electronically deficient (R-ax,S,S)-F-12-C-3-TunePhos and its applications in asymmetric 1,4-addition reactions".TETRAHEDRON LETTERS 57.17(2016):1925-1929.