New synthesis route for ternary transition metal amides as well as ultrafast amide-hydride hydrogen storage materials

doi:10.1039/c6cc00719h

	New synthesis route for ternary transition metal amides as well as ultrafast amide-hydride hydrogen storage materials
	Klassen, Thomas 1; Cao, Hujun 1; Santoru, Antonio 1; Pistidda, Claudio 1; Richter, Theresia M. M.2; Chaudhary, Anna-Lisa 1; Gizer, Goekhan 1; Niewa, Rainer 2; Chen, Ping 3; Dornheim, Martin 1
刊名	CHEMICAL COMMUNICATIONS
	2016
卷号	52 期号:29 页码:5100-5103
ISSN号	1359-7345
DOI	10.1039/c6cc00719h
文献子类	Article
英文摘要	K-2[Mn(NH2)(4)] and K-2[Zn(NH2)(4)] were successfully synthesized via a mechanochemical method. The mixture of K-2[Mn(NH2)(4)] and LiH showed excellent rehydrogenation properties. In fact, after dehydrogenation K-2[Mn(NH2)(4)]-8LiH fully rehydrogenates within 60 seconds at ca. 230 degrees C and 5 MPa of H-2. This is one of the fastest rehydrogenation rates in amide-hydride systems known to date. This work also shows a strategy for the synthesis of transition metal nitrides by decomposition of the mixtures of M[M'(NH2)(n)] (where M is an alkali or alkaline earth metal and M' is a transition metal) and metal hydrides.
WOS关键词	LITHIUM-ION BATTERIES ; MECHANOCHEMICAL SYNTHESIS ; CRYSTAL-STRUCTURE ; AMMONOTHERMAL SYNTHESIS ; MAGNETIC-PROPERTIES ; OPTICAL-PROPERTIES ; ANODE MATERIAL ; ZINC NITRIDE ; FUEL-CELLS ; SYSTEM
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000373629800003
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170722]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Cao, Hujun
作者单位	1.Helmholtz Zentrum Geesthacht GmbH, Inst Mat Res, Mat Technol, Max Planck Str 1, D-21502 Geesthacht, Schleswig Holst, Germany 2.Univ Stuttgart, Inst Inorgan Chem, Pfaffenwaldring 55, D-70569 Stuttgart, Germany 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Klassen, Thomas,Cao, Hujun,Santoru, Antonio,et al. New synthesis route for ternary transition metal amides as well as ultrafast amide-hydride hydrogen storage materials[J]. CHEMICAL COMMUNICATIONS,2016,52(29):5100-5103.
APA	Klassen, Thomas.,Cao, Hujun.,Santoru, Antonio.,Pistidda, Claudio.,Richter, Theresia M. M..,...&Dornheim, Martin.(2016).New synthesis route for ternary transition metal amides as well as ultrafast amide-hydride hydrogen storage materials.CHEMICAL COMMUNICATIONS,52(29),5100-5103.
MLA	Klassen, Thomas,et al."New synthesis route for ternary transition metal amides as well as ultrafast amide-hydride hydrogen storage materials".CHEMICAL COMMUNICATIONS 52.29(2016):5100-5103.