Ultrahigh energy storage and ultrafast ion diffusion in borophene-based anodes for rechargeable metal ion batteries | |
Liu, Jiehua4; Rao, Dewei2; Zhang, Lingyan3; Meng, Zhaoshun3; Zhang, Xirui3; Wang, Yunhui3; Qiao, Guanjun2; Shen, Xiangqian2; Xia, Hui1; Lu, Ruifeng1,3 | |
刊名 | JOURNAL OF MATERIALS CHEMISTRY A |
2017 | |
卷号 | 5期号:5页码:2328-2338 |
ISSN号 | 2050-7488 |
DOI | 10.1039/c6ta09730h |
文献子类 | Article |
英文摘要 | Since the turn of the new century, the increasing demand for high-performance energy storage systems has generated considerable interest in rechargeable ion batteries (IBs). However, current IB technologies are not entirely satisfactory, especially the electrodes. We report here, via density functional theory calculations and first principles molecular dynamics simulations, that a borophene anode material has the fascinating properties of ultrahigh energy storage and ultrafast ion diffusion in metal (Li, Na, K, Mg, Al) IBs. Particularly for Li IBs with a borophene anode, a specific density of 3306 mA h g(-1) and a high charging voltage of 1.46 V can be maintained at room temperature. Furthermore, non-ideal borophene anodes, including those with defects or oxidation and nanoribbon samples, still possess good properties for practical applications. This theoretical exploration will provide helpful guidance in searching for available or novel boron nanosheets as promising anode materials to advance commercial IB technology. |
WOS关键词 | HIGH-CAPACITY ANODE ; LITHIUM STORAGE ; DIRECTIONAL DIFFUSION ; GRAPHENE NANOSHEETS ; CYCLING STABILITY ; RATE CAPABILITY ; LI ; PHOSPHORENE ; NITROGEN ; MOS2 |
WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000395074300059 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169572] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Shen, Xiangqian; Xia, Hui; Lu, Ruifeng |
作者单位 | 1.Nanjing Univ Sci & Technol, Sch Mat Sci & Engn, Herbert Gleiter Inst Nanosci, Nanjing 210094, Peoples R China 2.Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China 3.Nanjing Univ Sci & Technol, Sch Sci, Atom Mol & Mat Phys Grp, Nanjing 210094, Peoples R China 4.Hefei Univ Technol, Sch Mat Sci & Engn, Future Energy Lab, Hefei 230009, Peoples R China 5.Dalian Inst Chem Phys, Chinese Acad Sci, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Jiehua,Rao, Dewei,Zhang, Lingyan,et al. Ultrahigh energy storage and ultrafast ion diffusion in borophene-based anodes for rechargeable metal ion batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(5):2328-2338. |
APA | Liu, Jiehua.,Rao, Dewei.,Zhang, Lingyan.,Meng, Zhaoshun.,Zhang, Xirui.,...&Lu, Ruifeng.(2017).Ultrahigh energy storage and ultrafast ion diffusion in borophene-based anodes for rechargeable metal ion batteries.JOURNAL OF MATERIALS CHEMISTRY A,5(5),2328-2338. |
MLA | Liu, Jiehua,et al."Ultrahigh energy storage and ultrafast ion diffusion in borophene-based anodes for rechargeable metal ion batteries".JOURNAL OF MATERIALS CHEMISTRY A 5.5(2017):2328-2338. |
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