A green route for methanol carbonylation

doi:10.1039/c7cy01621b

	A green route for methanol carbonylation
	Liu, Yong 1,2; Ni, Youming 1,2; Shi, Lei 1,2; Liu, Hongchao 1,2; Zhang, Wenna 1,2,3; Zhu, Wenliang 1,2; Liu, Zhongmin 1,2
刊名	CATALYSIS SCIENCE & TECHNOLOGY
	2017-10-21
卷号	7 期号:20 页码:4818-4822
ISSN号	2044-4753
DOI	10.1039/c7cy01621b
文献子类	Article
英文摘要	Acetic acid is one of the most important bulk commodity chemicals and is currently manufactured by methanol carbonylation reactions with rhodium or iridium organometallic complexes and halide-containing promoters named Monsanto or BP Cativa T homogeneous processes, respectively. Developing a halide-free catalyst and a heterogeneous process for methanol carbonylation is of great importance and has recently attracted extensive research attention. Here, we report a green route for direct synthesis of acetic acid via vapor-phase carbonylation of methanol with a stable, selective, halide-free, and noble metal-free catalyst based on pyridine-modified H-mordenite zeolite. Methanol conversion and acetic acid selectivity can reach up to 100% and 95%, respectively. Only little deactivation is observed during the 145 hour reaction.
WOS关键词	DIMETHYL ETHER CARBONYLATION ; SOLID ACID CATALYSTS ; METHYL ACETATE ; SELECTIVE CARBONYLATION ; MORDENITE ZEOLITE ; SPECIFICITY ; PROMOTION ; MECHANISM ; CHANNELS ; SITES
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000413192900023
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169220]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zhu, Wenliang; Liu, Zhongmin
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian, PR, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Yong,Ni, Youming,Shi, Lei,et al. A green route for methanol carbonylation[J]. CATALYSIS SCIENCE & TECHNOLOGY,2017,7(20):4818-4822.
APA	Liu, Yong.,Ni, Youming.,Shi, Lei.,Liu, Hongchao.,Zhang, Wenna.,...&Liu, Zhongmin.(2017).A green route for methanol carbonylation.CATALYSIS SCIENCE & TECHNOLOGY,7(20),4818-4822.
MLA	Liu, Yong,et al."A green route for methanol carbonylation".CATALYSIS SCIENCE & TECHNOLOGY 7.20(2017):4818-4822.