Access to Quaternary Stereogenic Centers via Rhodium(III)-Catalyzed Annulations between 2-Phenylindoles and Ketenes

doi:10.1021/acs.orglett.8b00497

	Access to Quaternary Stereogenic Centers via Rhodium(III)-Catalyzed Annulations between 2-Phenylindoles and Ketenes
	Yang, Xifa 1,2; Li, Yunyun 1,2; Kong, Lingheng 1,2; Li, Xingwei 2
刊名	ORGANIC LETTERS
	2018-04-06
卷号	20 期号:7 页码:1957-1960
ISSN号	1523-7060
DOI	10.1021/acs.orglett.8b00497
文献子类	Article
英文摘要	Rh(III)-catalyzed C-H activation of arenes and mild oxidative [4 + 2] annulative coupling with ketenes have been realized. The uniquely high reactivity of the C(3) of 2-phenylindoles was successfully utilized to facilitate the reductive elimination process, leading to efficient synthesis of cyclic products with a quaternary carbon stereocenter.
WOS关键词	C-H ACTIVATION ; CYCLATIVE CAPTURE APPROACH ; RH-CATALYZED ANNULATIONS ; CARBON-HYDROGEN BONDS ; CARBOXYLIC-ACIDS ; N-METHOXYBENZAMIDES ; INTERNAL ALKYNES ; DIAZO-COMPOUNDS ; REGIOSELECTIVE SYNTHESIS ; OXIDATIVE ANNULATION
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000429886900062
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169148]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Xingwei
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Yang, Xifa,Li, Yunyun,Kong, Lingheng,et al. Access to Quaternary Stereogenic Centers via Rhodium(III)-Catalyzed Annulations between 2-Phenylindoles and Ketenes[J]. ORGANIC LETTERS,2018,20(7):1957-1960.
APA	Yang, Xifa,Li, Yunyun,Kong, Lingheng,&Li, Xingwei.(2018).Access to Quaternary Stereogenic Centers via Rhodium(III)-Catalyzed Annulations between 2-Phenylindoles and Ketenes.ORGANIC LETTERS,20(7),1957-1960.
MLA	Yang, Xifa,et al."Access to Quaternary Stereogenic Centers via Rhodium(III)-Catalyzed Annulations between 2-Phenylindoles and Ketenes".ORGANIC LETTERS 20.7(2018):1957-1960.