Phenol preparation from catalytic pyrolysis of palm kernel shell at low temperatures
Chang, Guozhang1; Miao, Peng1; Yan, Ximin1; Wang, Guijin3; Guo, Qingjie1,2
刊名BIORESOURCE TECHNOLOGY
2018-04-01
卷号253页码:214-219
关键词Pks Low Temperature Pyrolysis Tg-ftir-ms Gc/ms Phenol
ISSN号0960-8524
DOI10.1016/j.biortech.2017.12.084
文献子类Article
英文摘要In the present study, the characteristics of phenol preparation from palm kernel shell (PKS) pyrolysis at the temperature range of 265-320 degrees C were investigated using TG-FTIR-MS analyses, based on the analysis about the decomposition characteristics of PKS comparing to other biomass samples. The GC-MS analysis was subsequently employed to qualitatively and quantitatively characterize the phenol in bio-oils from PKS catalytic pyrolysis at 265-320 degrees C. Two significant weight loss peaks with the closer values were observed in DTG curve of PKS that differentiated with other samples, which was mainly attributed to the content and especially the structural characteristics of lignin in the PKS. Phenol was mainly in bio-oils from decomposition of the "first weight loss peak" during PKS pyrolysis at 265-320 degrees C. The relative content in bio-oil, selectivity in phenolic compounds, and mass yield of phenol from PKS catalytic pyrolysis with CaO could reach to 83.21 area%, 100%, and 0.0075 g/(g biomass), respectively.
WOS关键词RICH BIO-OIL ; LIGNIN PYROLYSIS ; FIXED-BED ; PY-GC/MS ; TGA-FTIR ; BEHAVIORS ; KINETICS ; SAWDUST
WOS研究方向Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000426155700027
内容类型期刊论文
源URL[http://cas-ir.dicp.ac.cn/handle/321008/168726]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Guo, Qingjie
作者单位1.Qingdao Univ Sci & Technol, Coll Chem Engn, Key Lab Clean Chem Proc Shandong Prov, Qingdao 266042, Peoples R China
2.Ningxia Univ, Coll Chem & Chem Engn, State Key Lab High Efficiency Coal Utilizat & Gre, Yinchuan 750021, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Chang, Guozhang,Miao, Peng,Yan, Ximin,et al. Phenol preparation from catalytic pyrolysis of palm kernel shell at low temperatures[J]. BIORESOURCE TECHNOLOGY,2018,253:214-219.
APA Chang, Guozhang,Miao, Peng,Yan, Ximin,Wang, Guijin,&Guo, Qingjie.(2018).Phenol preparation from catalytic pyrolysis of palm kernel shell at low temperatures.BIORESOURCE TECHNOLOGY,253,214-219.
MLA Chang, Guozhang,et al."Phenol preparation from catalytic pyrolysis of palm kernel shell at low temperatures".BIORESOURCE TECHNOLOGY 253(2018):214-219.
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