The cooperation of porphyrin-based porous polymer and thermal-responsive ionic liquid for efficient CO2 cycloaddition reaction

doi:10.1039/c7gc03801a

	The cooperation of porphyrin-based porous polymer and thermal-responsive ionic liquid for efficient CO2 cycloaddition reaction
	Chen, Jian 1,2; Zhong, Mingmei 1,2; Tao, Lin 1,2; Liu, Lina 1,2; Jayakumar, Sanjeevi 1,3; Li, Chunzhi 1,2; Li, He 1; Yang, Qihua 1
刊名	GREEN CHEMISTRY
	2018-02-21
卷号	20 期号:4 页码:903-911
ISSN号	1463-9262
DOI	10.1039/c7gc03801a
文献子类	Article
英文摘要	The cooperation of catalyst and co-catalyst, together with efficient recycling, is one of the most important and still big challenges for CO2 cycloaddition reaction. Herein, we report a facile and atom-efficient method to synthesize a porous zinc-porphyrin-based framework (P-POF-Zn) as a catalyst for the synthesis of cyclic carbonates. It was demonstrated for the first time that the combination of P-POF-Zn and thermal-responsive ionic liquid [CPeDMAPy] Br (soluble in PO and PC at high temperature but not at room temperature) could efficiently catalyze the cycloaddition reaction of CO2 and propylene oxide to afford a turnover frequency of 433 h(-1). The high catalytic activity is mainly attributed to the efficient cooperation of P-POF-Zn (Lewis acid site) and [CPeDMAPy] Br (nucleophile). Both P-POF-Zn and [CPeDMAPy] Br could be fully recovered after reaction by simple filtration for stable recycling. This work demonstrates the efficiency of the combination of thermal-responsive reagents with solid catalyst for catalyzing chemical reactions via a cooperation activation pathway.
WOS关键词	CARBON-DIOXIDE CAPTURE ; CYCLIC CARBONATES ; HETEROGENEOUS CATALYST ; ORGANIC POLYMER ; METALLOPORPHYRIN POLYMERS ; PROPYLENE CARBONATE ; AMBIENT CONDITIONS ; GRAPHENE OXIDE ; FLUE-GAS ; CONVERSION
WOS研究方向	Chemistry ; Science & Technology - Other Topics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000425466900019
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168680]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, He; Yang, Qihua
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, iChEM, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Univ Chinese Acad Sci, Int Coll, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Chen, Jian,Zhong, Mingmei,Tao, Lin,et al. The cooperation of porphyrin-based porous polymer and thermal-responsive ionic liquid for efficient CO2 cycloaddition reaction[J]. GREEN CHEMISTRY,2018,20(4):903-911.
APA	Chen, Jian.,Zhong, Mingmei.,Tao, Lin.,Liu, Lina.,Jayakumar, Sanjeevi.,...&Yang, Qihua.(2018).The cooperation of porphyrin-based porous polymer and thermal-responsive ionic liquid for efficient CO2 cycloaddition reaction.GREEN CHEMISTRY,20(4),903-911.
MLA	Chen, Jian,et al."The cooperation of porphyrin-based porous polymer and thermal-responsive ionic liquid for efficient CO2 cycloaddition reaction".GREEN CHEMISTRY 20.4(2018):903-911.