Selective Electrochemical Reduction of Carbon Dioxide Using Cu Based Metal Organic Framework for CO2 Capture

doi:10.1021/acsami.7b15255

	Selective Electrochemical Reduction of Carbon Dioxide Using Cu Based Metal Organic Framework for CO2 Capture
	Qiu, Yan-Ling 2; Zhong, He-Xiang 2,3; Zhang, Tao-Tao 1,2; Xu, Wen-Bin 2; Su, Pan-Pan 2; Li, Xian-Feng 2,3; Zhang, Hua-Min 2,3
刊名	ACS APPLIED MATERIALS & INTERFACES
	2018-01-24
卷号	10 期号:3 页码:2480-2489
关键词	Carbon Dioxide Electroreduction Co2 Solubility Co2 Capture Faradaic Efficiency Gas Diffusion Electrode
ISSN号	1944-8244
DOI	10.1021/acsami.7b15255
文献子类	Article
英文摘要	The conversion efficiency and product selectivity of the electroreduction of carbon dioxide have been largely limited by the low CO2 solubility in aqueous solution. To relieve this problem, Cu-3(BTC)(2) (Cu-MOF) as CO2 capture agent was introduced into a carbon paper based gas diffusion electrode (GDE) in this study. The faradaic efficiencies (FEs) of CH4 on GDE with Cu-MOF weight ratio in the range of 7.5-10% are 2-3-fold higher than that of GDE without Cu-MOF addition under negative potentials (-2.3 to -2.5 V vs SCE), and the FE of the competitive hydrogen evolution reaction (HER) is reduced to 30%. This work paves the way to develop GDE with high catalytic activity for ERC.
WOS关键词	GAS-DIFFUSION ELECTRODES ; ZEOLITIC IMIDAZOLATE FRAMEWORKS ; ELECTROCATALYTIC REDUCTION ; HIGH-PRESSURE ; COPPER ; ELECTROREDUCTION ; ETHYLENE ; SEPARATION ; NANOWIRES ; CATALYSTS
WOS研究方向	Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000423496500035
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168640]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Xian-Feng; Zhang, Hua-Min
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Zhongshan Rd 457, Dalian 116023, Peoples R China 3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Qiu, Yan-Ling,Zhong, He-Xiang,Zhang, Tao-Tao,et al. Selective Electrochemical Reduction of Carbon Dioxide Using Cu Based Metal Organic Framework for CO2 Capture[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(3):2480-2489.
APA	Qiu, Yan-Ling.,Zhong, He-Xiang.,Zhang, Tao-Tao.,Xu, Wen-Bin.,Su, Pan-Pan.,...&Zhang, Hua-Min.(2018).Selective Electrochemical Reduction of Carbon Dioxide Using Cu Based Metal Organic Framework for CO2 Capture.ACS APPLIED MATERIALS & INTERFACES,10(3),2480-2489.
MLA	Qiu, Yan-Ling,et al."Selective Electrochemical Reduction of Carbon Dioxide Using Cu Based Metal Organic Framework for CO2 Capture".ACS APPLIED MATERIALS & INTERFACES 10.3(2018):2480-2489.