Synthesis, characterization and properties of a glycol-coordinated epsilon-Keggin-type Al-13 chloride

doi:10.1039/c8cc01363b

	Synthesis, characterization and properties of a glycol-coordinated epsilon-Keggin-type Al-13 chloride
	Gu, Bin 2; Sun, Chenglin 2; Fettinger, James C.3; Casey, William H.3; Dikhtiarenko, Alla 4; Gascon, Jorge 4; Koichumanova, Kamila 5; Gupta, Karthick Babu Sai Sankar 6; Heeres, Hero Jan 1; He, Songbo 1
刊名	CHEMICAL COMMUNICATIONS
	2018-04-21
卷号	54 期号:33 页码:4148-4151
ISSN号	1359-7345
DOI	10.1039/c8cc01363b
文献子类	Article
英文摘要	Herein we present the first example of a glycol-coordinated epsilon-Keggin Al-13 chloride (gl-epsilon-Al-13), which is the first chelated version since discovery of Al-13 in 1960. The molecular structure consists of [AlO4Al12(OH)(12)(OC2H4OH)(12)]Cl-7 center dot H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.
WOS关键词	SELECTIVE N-ALKYLATION ; BORROWING HYDROGEN METHODOLOGY ; AL-27 NMR-SPECTROSCOPY ; CRYSTAL STRUCTURE ; BENZYL ALCOHOL ; GAMMA-ALUMINA ; AMINES ; HYDROXIDE ; CLUSTER ; ISOMERIZATION
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000430538500015
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/167188]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Sun, Chenglin; He, Songbo
作者单位	1.Univ Groningen, Green Chem React Engn, NL-9747 AG Groningen, Netherlands 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Calif Davis, Dept Chem, Davis, CA 95616 USA 4.King Abdullah Univ Sci & Technol, KAUST Catalysis Ctr, Adv Catalyt Mat, Thuwal 23955, Saudi Arabia 5.Univ Amsterdam, Fac Sci, NL-1090 GS Amsterdam, Netherlands 6.Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands
推荐引用方式 GB/T 7714	Gu, Bin,Sun, Chenglin,Fettinger, James C.,et al. Synthesis, characterization and properties of a glycol-coordinated epsilon-Keggin-type Al-13 chloride[J]. CHEMICAL COMMUNICATIONS,2018,54(33):4148-4151.
APA	Gu, Bin.,Sun, Chenglin.,Fettinger, James C..,Casey, William H..,Dikhtiarenko, Alla.,...&He, Songbo.(2018).Synthesis, characterization and properties of a glycol-coordinated epsilon-Keggin-type Al-13 chloride.CHEMICAL COMMUNICATIONS,54(33),4148-4151.
MLA	Gu, Bin,et al."Synthesis, characterization and properties of a glycol-coordinated epsilon-Keggin-type Al-13 chloride".CHEMICAL COMMUNICATIONS 54.33(2018):4148-4151.