Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2

doi:10.1002/anie.201808926

	Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2
	Lu, Xing 2; Gan, Liangbing 1,3; Li, Yanbang 1; Lou, Ning 1; Xu, Dan 1; Pan, Changwang 2
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2018-10-22
卷号	57 期号:43 页码:14144-14148
关键词	encapsulation fullerenes hydrogen peroxide molecular containers open-cage fullerenes
ISSN号	1433-7851
DOI	10.1002/anie.201808926
通讯作者	Lu, Xing(lux@hust.edu.cn) ; Gan, Liangbing(gan@pku.edu.cn)
英文摘要	An open-cage [60]fullerene was prepared through a multiple-step sequence based on peroxide-mediated cage-opening reactions. Key steps include repeated C-60-sensitized singlet-oxygen oxidation of electron-rich amino enol double bonds to form two lactone and two lactam moieties on the rim of the orifice. Single-crystal X-ray analysis shows that the 22-membered orifice has an ellipsoid shape with the major axis at 6.7 angstrom and the minor axis at 3.5 angstrom. Encapsulation of H2O2 was observed under atmospheric pressure at room temperature. Oxygen is also effectively trapped during the process.
资助项目	NNSFC[21132007] ; NNSFC[21672009] ; NNSFC[51472095] ; NNSFC[51672093] ; MOST[2015CB856600]
WOS关键词	MOLECULAR-HYDROGEN ; CARBON-ATOM ; C-60 ; CYANIDE
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000447371500027
资助机构	NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166928]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Lu, Xing; Gan, Liangbing
作者单位	1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Huazhong Univ Sci & Technol, State Key Lab Mat Proc & Die & Mould Technol, Sch Mat Sci & Engn, 1037 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China 3.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Lu, Xing,Gan, Liangbing,Li, Yanbang,et al. Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(43):14144-14148.
APA	Lu, Xing,Gan, Liangbing,Li, Yanbang,Lou, Ning,Xu, Dan,&Pan, Changwang.(2018).Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(43),14144-14148.
MLA	Lu, Xing,et al."Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.43(2018):14144-14148.