Palladium-Catalyzed C-S Bond Cleavage with Allenoates: Synthesis of Tetrasubstituted 2-Alkenylfuran Derivatives

doi:10.1021/acs.orglett.8b02253

	Palladium-Catalyzed C-S Bond Cleavage with Allenoates: Synthesis of Tetrasubstituted 2-Alkenylfuran Derivatives
	Liu, Zhuqing 1,2; Yu, Zhengkun 1,3; Wang, Quannan 1,2; Lou, Jiang 1,2
刊名	ORGANIC LETTERS
	2018-10-05
卷号	20 期号:19 页码:6007-6011
ISSN号	1523-7060
DOI	10.1021/acs.orglett.8b02253
通讯作者	Yu, Zhengkun(zkyu@dicp.ac.cn)
英文摘要	Palladium-catalyzed C-S cleavage of tetrasubstituted internal alkene alpha-oxo ketene dithioacetals was realized with allenoates as the coupling partners, efficiently affording tetrasubstituted 2-alkenylfuran derivatives with excellent regioselectivity under mild conditions. Allenoates acted as C1 synthons in the desulfurative [4 + 1] annulation.
资助项目	National Basic Research Program of China[2015CB856600] ; National Natural Science Foundation of China[21472185] ; National Natural Science Foundation of China[21871253]
WOS关键词	OXO KETENE DITHIOACETALS ; EFFICIENT SYNTHESIS ; POLYSUBSTITUTED FURANS ; CYCLIZATION REACTION ; INTERNAL OLEFINS ; STEREOSELECTIVE-SYNTHESIS ; COUMESTAN DERIVATIVES ; H FUNCTIONALIZATION ; 1,2-ALLENYL KETONES ; HOMOALLENYL AMIDES
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000447118200006
资助机构	National Basic Research Program of China ; National Basic Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Basic Research Program of China ; National Basic Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Basic Research Program of China ; National Basic Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Basic Research Program of China ; National Basic Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166902]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Yu, Zhengkun
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Liu, Zhuqing,Yu, Zhengkun,Wang, Quannan,et al. Palladium-Catalyzed C-S Bond Cleavage with Allenoates: Synthesis of Tetrasubstituted 2-Alkenylfuran Derivatives[J]. ORGANIC LETTERS,2018,20(19):6007-6011.
APA	Liu, Zhuqing,Yu, Zhengkun,Wang, Quannan,&Lou, Jiang.(2018).Palladium-Catalyzed C-S Bond Cleavage with Allenoates: Synthesis of Tetrasubstituted 2-Alkenylfuran Derivatives.ORGANIC LETTERS,20(19),6007-6011.
MLA	Liu, Zhuqing,et al."Palladium-Catalyzed C-S Bond Cleavage with Allenoates: Synthesis of Tetrasubstituted 2-Alkenylfuran Derivatives".ORGANIC LETTERS 20.19(2018):6007-6011.