Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids

doi:10.1039/c8cc06820h

	Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids
	Wang, Meng-Meng; Li, Can; Paridala, Kumaraswamy; Lu, Sheng-Mei
刊名	CHEMICAL COMMUNICATIONS
	2018-10-21
卷号	54 期号:82 页码:11574-11577
ISSN号	1359-7345
DOI	10.1039/c8cc06820h
通讯作者	Li, Can(canli@dicp.ac.cn)
英文摘要	The present study discloses the synthesis of aryl/vinyl carboxylic acids from Csp(2)-bound halides (Cl, Br, I) in a carbonylative path by using silyl formate (from CO2 and hydrosilane) as an instant CO-surrogate. Hydrosilane provides hydride for reduction and its oxidation product silanol serves as a coupling partner. Mono-, di-, and tri-carboxylic acids were obtained from the corresponding aryl/vinyl halides.
WOS关键词	METAL-CATALYZED CARBOXYLATION ; CARBON-DIOXIDE ; HYDROSILYLATION ; HYDROFORMYLATION ; TRANSFORMATION ; SURROGATES
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000447181600013
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166860]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Can
作者单位	Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Zhongshan Rd 457, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Wang, Meng-Meng,Li, Can,Paridala, Kumaraswamy,et al. Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids[J]. CHEMICAL COMMUNICATIONS,2018,54(82):11574-11577.
APA	Wang, Meng-Meng,Li, Can,Paridala, Kumaraswamy,&Lu, Sheng-Mei.(2018).Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids.CHEMICAL COMMUNICATIONS,54(82),11574-11577.
MLA	Wang, Meng-Meng,et al."Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids".CHEMICAL COMMUNICATIONS 54.82(2018):11574-11577.