Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds

doi:10.1039/c8cc07764a

	Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds
	Xue, Yazhen 1; Huo, Jingfeng 1; Wang, Jianbo 1,2
刊名	CHEMICAL COMMUNICATIONS
	2018-11-07
卷号	54 期号:86 页码:12266-12269
ISSN号	1359-7345
DOI	10.1039/c8cc07764a
通讯作者	Wang, Jianbo(wangjb@pku.edu.cn)
英文摘要	A Cu(I)-catalyzed aminoborylation reaction of styrenes is reported. In this transformation, diazo compounds are used as the electrophilic amination agent. The in situ generated benzylcopper species is trapped by the electrophilic nitrogen terminus of the diazo substrate to afford borylated hydrazones in a regioselective manner.
资助项目	973 Program[2015CB856600] ; NSFC[21332002]
WOS关键词	UNACTIVATED TERMINAL ALKENES ; AMINOBORATION ; INSERTION ; ESTERS ; ELECTROPHILES ; NITROGEN ; BONDS
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000448501400029
资助机构	973 Program ; 973 Program ; NSFC ; NSFC ; 973 Program ; 973 Program ; NSFC ; NSFC ; 973 Program ; 973 Program ; NSFC ; NSFC ; 973 Program ; 973 Program ; NSFC ; NSFC
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166794]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Jianbo
作者单位	1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Xue, Yazhen,Huo, Jingfeng,Wang, Jianbo. Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds[J]. CHEMICAL COMMUNICATIONS,2018,54(86):12266-12269.
APA	Xue, Yazhen,Huo, Jingfeng,&Wang, Jianbo.(2018).Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds.CHEMICAL COMMUNICATIONS,54(86),12266-12269.
MLA	Xue, Yazhen,et al."Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds".CHEMICAL COMMUNICATIONS 54.86(2018):12266-12269.