Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes

doi:10.1039/c8cp03672a

	Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes
	Yang, Xueming 2; Lei, Xin 1,2; Kong, Xiangtao 2; Zhao, Zhi 2; Zhang, Bingbing 1,2; Dai, Dongxu 2; Jiang, Ling 2
刊名	PHYSICAL CHEMISTRY CHEMICAL PHYSICS
	2018-10-28
卷号	20 期号:40 页码:9
ISSN号	1463-9076
DOI	10.1039/c8cp03672a
通讯作者	Jiang, Ling(ljiang@dicp.ac.cn)
英文摘要	Cryogenic ion-trap infrared photodissociation spectroscopy combined with a dielectric barrier discharge source was constructed to establish the general trends in the stepwise growth motif of trimethylamine (TMA)(n)(+) complexes. The results showed a strong preference for the formation of a stable charge-shared NN type (TMA)(2)(+) ion core over the proton-transferred CHN type ion core, evidencing that the source condition has a remarkable effect on the kinetic stability of isomers. A maximum of four TMA molecules are located perpendicularly to the NN axis of the charge-shared (TMA)(2)(+) ion core. In the n = 7 and 8 clusters, the subsequent two TMA molecules are located at each end of the NN axis of the (TMA)(2)(+) ion core, completing the first coordination shell. Starting at n = 9, the additional TMA molecules form a second solvation shell, and the cluster spectra show similarities to the solution phase spectrum of aqueous TMA.
资助项目	National Natural Science Foundation of China[21673231] ; National Natural Science Foundation of China[21688102] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17000000] ; Hundred Talents Program of Chinese Academy of Sciences
WOS关键词	PHOTOELECTRON-SPECTROSCOPY ; VIBRATIONAL SPECTROSCOPY ; BONDED CLUSTERS ; DIMER ; ANION ; NUCLEATION ; MOLECULES ; CHEMISTRY ; DIANIONS ; SPECTRUM
WOS研究方向	Chemistry ; Physics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000448345800003
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166764]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Jiang, Ling
作者单位	1.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Yang, Xueming,Lei, Xin,Kong, Xiangtao,et al. Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2018,20(40):9.
APA	Yang, Xueming.,Lei, Xin.,Kong, Xiangtao.,Zhao, Zhi.,Zhang, Bingbing.,...&Jiang, Ling.(2018).Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,20(40),9.
MLA	Yang, Xueming,et al."Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 20.40(2018):9.