Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications

doi:10.1016/j.ccr.2017.10.025

	Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications
	Zhang, Jiangwei 1,2,3; Huang, Yichao 2; Li, Gao 1,3; Wei, Yongge 2
刊名	COORDINATION CHEMISTRY REVIEWS
	2019
卷号	378 页码:395-414
关键词	Polyoxometalates POMs-based materials Alkoxylation Organic functionalization Tris ligands
ISSN号	0010-8545
DOI	10.1016/j.ccr.2017.10.025
通讯作者	Li, Gao(gaoli@dicp.ac.cn) ; Wei, Yongge(yonggewei@mail.tsinghua.edu.cn)
英文摘要	Polyoxometalates (POMs), an exceptional family of coordination clusters consisting of Mo, W, V, etc. early transition metal ions in their highest oxidation states, have received significant attention over recent years due to their structural versatility and unique and diverse chemical and physical properties. The functionalization of POMs with organic ligands provides a novel strategy to precisely incorporate POMs with advanced functional organic moieties on their surfaces and enhance their compatibility in organic media. Among the various organically functionalized synthetic strategies for POM-based organic-inorganic hybrid materials, alkoxylation of POMs stands for one of the hottest topics during the past decades, since the diverse and tunable alkoxyl ligands are able to anchor on the surface of many POMs clusters, forming novel and flexible organically functionalized POM clusters, which can be further exploited as building blocks to design various functionalized POM-based hybrids with charming catalytic properties, and biomedicine, energy, or functional materials applications. In this review, recent advances in alkoxylation chemistry of POMs from synthetic strategies, structural overviews to their functional applications have been discussed. (C) 2017 Elsevier B.V. All rights reserved.
资助项目	National Natural Science Foundation of China (NSFC)[21471087] ; National Natural Science Foundation of China (NSFC)[21631007] ; National Natural Science Foundation of China (NSFC)[21225103] ; National Natural Science Foundation of China (NSFC)[21701168] ; Liaoning Natural Science Foundation[20170540897] ; fund of the Thousand Youth Talents Plan
WOS关键词	ANDERSON-TYPE POLYOXOMETALATE ; MIXED-VALENCE ; ORGANIC HYBRID ; POST-FUNCTIONALIZATION ; HETEROGENEOUS CATALYSTS ; ORGANOIMIDO DERIVATIVES ; CONTROLLABLE SYNTHESIS ; ASSISTED SYNTHESIS ; HEXAMETALATE CORE ; BUILDING-BLOCKS
WOS研究方向	Chemistry
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000451498300022
资助机构	National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166574]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Gao; Wei, Yongge
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Gold Catalysis Res Ctr, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Jiangwei,Huang, Yichao,Li, Gao,et al. Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications[J]. COORDINATION CHEMISTRY REVIEWS,2019,378:395-414.
APA	Zhang, Jiangwei,Huang, Yichao,Li, Gao,&Wei, Yongge.(2019).Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications.COORDINATION CHEMISTRY REVIEWS,378,395-414.
MLA	Zhang, Jiangwei,et al."Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications".COORDINATION CHEMISTRY REVIEWS 378(2019):395-414.