NiFe Hydroxide Lattice Tensile Strain: Enhancement of Adsorption of Oxygenated Intermediates for Efficient Water Oxidation Catalysis

doi:10.1002/anie.201809689

	NiFe Hydroxide Lattice Tensile Strain: Enhancement of Adsorption of Oxygenated Intermediates for Efficient Water Oxidation Catalysis
	Yang, Hongbin 2,4; Zhou, Daojin 1,2; Wang, Shiyuan 1,3; Jia, Yin 1,3; Xiong, Xuya 1; Liu, Song 5; Tang, Jialun 6; Zhang, Junming 2; Liu, Dong 2; Zheng, Lirong 7
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2019-01-14
卷号	58 期号:3 页码:736-740
关键词	ball-milling NiFe catalysts oxygen evolution tensile strain
ISSN号	1433-7851
DOI	10.1002/anie.201809689
通讯作者	Kuang, Yun(kuangyun@mail.buct.edu.cn) ; Sun, Xiaoming(sunxm@mail.buct.edu.cn) ; Liu, Bin(liubin@ntu.edu.sg)
英文摘要	The binding strength of reactive intermediates with catalytically active sites plays a crucial role in governing catalytic performance of electrocatalysts. NiFe hydroxide offers efficient oxygen evolution reaction (OER) catalysis in alkaline electrolyte, however weak binding of oxygenated intermediates on NiFe hydroxide still badly limits its catalytic activity. Now, a facile ball-milling method was developed to enhance binding strength of NiFe hydroxide to oxygenated intermediates via generating tensile strain, which reduced the anti-bonding filling states in the d orbital and thus facilitated oxygenated intermediates adsorption. The NiFe hydroxide with tensile strain increasing after ball-milling exhibits an OER onset potential as low as 1.44 V (vs. reversible hydrogen electrode) and requires only a 270 mV overpotential to reach a water oxidation current density of 10 mA cm(-2).
资助项目	National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in the University ; Fundamental Research Funds for the Central Universities ; Ministry of Finance ; Ministry of Education of China ; National Key Research and Development Project[2016YFF0204402] ; Singapore Ministry of Education Academic Research Fund (AcRF)[RG10/16] ; Singapore Ministry of Education Academic Research Fund (AcRF)[RG9/17] ; Singapore Ministry of Education Academic Research Fund (AcRF)[RG115/17] ; Singapore Ministry of Education Academic Research Fund (AcRF)[MOE2016-T2-2-004] ; Nanyang Technological University
WOS关键词	EVOLUTION REACTION ; OXIDE CATALYSTS ; METAL-OXIDES ; FE-SITES ; REDUCTION ; ELECTROCHEMISTRY ; ELECTROCATALYSTS ; IDENTIFICATION ; NANOPARTICLES ; REACTIVITY
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000455033700011
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in the University ; Program for Changjiang Scholars and Innovative Research Team in the University ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Ministry of Finance ; Ministry of Finance ; Ministry of Education of China ; Ministry of Education of China ; National Key Research and Development Project ; National Key Research and Development Project ; Singapore Ministry of Education Academic Research Fund (AcRF) ; Singapore Ministry of Education Academic Research Fund (AcRF) ; Nanyang Technological University ; Nanyang Technological University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in the University ; Program for Changjiang Scholars and Innovative Research Team in the University ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Ministry of Finance ; Ministry of Finance ; Ministry of Education of China ; Ministry of Education of China ; National Key Research and Development Project ; National Key Research and Development Project ; Singapore Ministry of Education Academic Research Fund (AcRF) ; Singapore Ministry of Education Academic Research Fund (AcRF) ; Nanyang Technological University ; Nanyang Technological University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in the University ; Program for Changjiang Scholars and Innovative Research Team in the University ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Ministry of Finance ; Ministry of Finance ; Ministry of Education of China ; Ministry of Education of China ; National Key Research and Development Project ; National Key Research and Development Project ; Singapore Ministry of Education Academic Research Fund (AcRF) ; Singapore Ministry of Education Academic Research Fund (AcRF) ; Nanyang Technological University ; Nanyang Technological University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in the University ; Program for Changjiang Scholars and Innovative Research Team in the University ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Ministry of Finance ; Ministry of Finance ; Ministry of Education of China ; Ministry of Education of China ; National Key Research and Development Project ; National Key Research and Development Project ; Singapore Ministry of Education Academic Research Fund (AcRF) ; Singapore Ministry of Education Academic Research Fund (AcRF) ; Nanyang Technological University ; Nanyang Technological University
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166366]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Kuang, Yun; Sun, Xiaoming; Liu, Bin
作者单位	1.Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore 3.Beijing Univ Chem Technol, Coll Energy, Beijing 100029, Peoples R China 4.Suzhou Univ Sci & Technol, Inst Mat Sci & Devices, Suzhou 215009, Peoples R China 5.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 6.Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Nanophoton & Ultrafine Optoelect, Beijing 100029, Peoples R China 7.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yang, Hongbin,Zhou, Daojin,Wang, Shiyuan,et al. NiFe Hydroxide Lattice Tensile Strain: Enhancement of Adsorption of Oxygenated Intermediates for Efficient Water Oxidation Catalysis[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(3):736-740.
APA	Yang, Hongbin.,Zhou, Daojin.,Wang, Shiyuan.,Jia, Yin.,Xiong, Xuya.,...&Liu, Bin.(2019).NiFe Hydroxide Lattice Tensile Strain: Enhancement of Adsorption of Oxygenated Intermediates for Efficient Water Oxidation Catalysis.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(3),736-740.
MLA	Yang, Hongbin,et al."NiFe Hydroxide Lattice Tensile Strain: Enhancement of Adsorption of Oxygenated Intermediates for Efficient Water Oxidation Catalysis".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.3(2019):736-740.