Asymmetric dual-phase MIEC membrane reactor for energy-efficient coproduction of two kinds of synthesis gases | |
Li, Hongbo1; Zhu, Xuefeng1; Yang, Weishen1; Li, Wenping1,2; Cao, Zhongwei1 | |
刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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2019-02-08 | |
卷号 | 44期号:8页码:4218-4227 |
关键词 | Asymmetric dual-phase membrane Membrane reactor Ammonia synthesis gas Liquid fuels synthesis gas Partial oxidation of methane Water splitting |
ISSN号 | 0360-3199 |
DOI | 10.1016/j.ijhydene.2018.12.182 |
通讯作者 | Zhu, Xuefeng(zhuxf@dicp.ac.cn) |
英文摘要 | An asymmetric 75 wt% Sm0.15Ce0.85O1.925-25 wt% Sm0.6Sr0.4Al0.3Fe0.7O3-delta (SDC-SSAF) dual-phase mixed ionic-electronic conducting (MIEC) oxygen-permeable membrane reactor was applied to coproduce ammonia synthesis gas (ASG, H-2/N-2 = 3) and liquid fuels synthesis gas (LFSG, H-2/CO = 2). The effects of CH4 concentration, CH4 flow rate, steam flow rate and temperature on the performance of the membrane reactor were studied. The SDC-SSAF membrane reactor showed an excellent performance for the coproduction of ASG and LFSG. An ASG production rate of 20.7 mL cm(-2) min(-1), a LFSG production rate of 51.0 mL cm(-2) min(-1) and an oxygen permeation rate of 9.1 mL cm(-2) min(-1) were achieved at 925 degrees C. Compared with traditional industrial processes, the energy saving of this membrane reactor process is expected as high as 66.5%. The post-mortem of the membrane reactor using scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) characterization revealed that the membrane has an excellent structural stability under operation condition. |
资助项目 | National Natural Science Foundation of China[91545202] ; National Natural Science Foundation of China[U1508203] ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS)[XDB17000000] ; project of Dalian Outstanding Young Scientific and Technical Talents[2016RJ07] ; DICP[DICP DMTO201503] |
WOS关键词 | OXYGEN PERMEATION PROPERTIES ; PARTIAL OXIDATION ; CERAMIC MEMBRANES ; METHANE ; WATER ; SEPARATION ; SYNGAS ; PERFORMANCE ; PEROVSKITE ; HYDROGEN |
WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000458224700020 |
资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; DICP ; DICP |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166098] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Zhu, Xuefeng |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Hongbo,Zhu, Xuefeng,Yang, Weishen,et al. Asymmetric dual-phase MIEC membrane reactor for energy-efficient coproduction of two kinds of synthesis gases[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2019,44(8):4218-4227. |
APA | Li, Hongbo,Zhu, Xuefeng,Yang, Weishen,Li, Wenping,&Cao, Zhongwei.(2019).Asymmetric dual-phase MIEC membrane reactor for energy-efficient coproduction of two kinds of synthesis gases.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,44(8),4218-4227. |
MLA | Li, Hongbo,et al."Asymmetric dual-phase MIEC membrane reactor for energy-efficient coproduction of two kinds of synthesis gases".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 44.8(2019):4218-4227. |
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