Production of 1,2-Cyclohexanedicarboxylates from Diacetone Alcohol and Fumarates

doi:10.1021/acssuschemeng.8b04310

	Production of 1,2-Cyclohexanedicarboxylates from Diacetone Alcohol and Fumarates
	Liang, Xinmiao 1,3; Li, Ning 1,5; Li, Wei 4; Hu, Yancheng 1; Yuan, Lin 1,2; Zhang, Xiuli 1,3; Zhou, Han 1,3; Wang, Pan 1,3; Li, Guangyi 1; Wang, Aiqin 1
刊名	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
	2019-02-04
卷号	7 期号:3 页码:2980-2988
关键词	Plasticizers Diacetone alcohol Fumarates Dehydration/Diels-Alder reaction Hydrogenation 1,2-Cyclohexanedicarboxylate
ISSN号	2168-0485
DOI	10.1021/acssuschemeng.8b04310
通讯作者	Li, Wei(liwei820927@nefu.edu.cn) ; Li, Ning(lining@dicp.ac.cn)
英文摘要	1,2-Cyclohexanedicarboxylates, which are one of the most commonly used plasticizers in the poly(vinyl chloride) (PVC) industry, are generally prepared via the oxidation/esterification/hydrogenation of o-xylene (or naphthalene). Herein, we develop an alternative route toward cyclohexane-based plasticizers using diacetone alcohol and fumarates as the starting materials. The process includes a mild Raney Ni-catalyzed hydrogenation of diacetone alcohol, an one-step dehydration/Diels-Alder reaction of resulting 2-methyl-2,4-pentandiol and fumarates in a choline chloride (ChCl) based deep eutectic solvent (DES), and a further Pd/C-catalyzed hydrogenation. The toxicological tests indicate that the as-synthesized di(2-ethylhexyl) 3,5-dimethylcyclohexane-1,2-dicarboxylate can serve as a safe plasticizer for PVC materials.
资助项目	National Natural Science Foundation of China[21690082] ; National Natural Science Foundation of China[21776273] ; National Natural Science Foundation of China[21721004] ; National Natural Science Foundation of China[21801239] ; DNL Cooperation Fund, CAS[DNL180301] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020100] ; National Key Projects for Fundamental Research and Development of China[2016YFA0202801] ; Dalian Science Foundation for Distinguished Young Scholars[201511005]
WOS关键词	SUSTAINABLE PRODUCTION ; CATALYTIC CONVERSION ; PLATFORM CHEMICALS ; MALEIC-ANHYDRIDE ; ETHYLENE-GLYCOL ; BIOMASS ; ACID ; PINACOL ; FUELS ; CONDENSATION
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Engineering
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000458086100015
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166068]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Ning; Li, Wei
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Key Lab Separat Sci Analyt Chem, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 4.Northeast Forestry Univ, Key Lab Biobased Mat Sci & Technol, Minist Educ, Hexing Rd 26, Harbin 150040, Heilongjiang, Peoples R China 5.Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Liang, Xinmiao,Li, Ning,Li, Wei,et al. Production of 1,2-Cyclohexanedicarboxylates from Diacetone Alcohol and Fumarates[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019,7(3):2980-2988.
APA	Liang, Xinmiao.,Li, Ning.,Li, Wei.,Hu, Yancheng.,Yuan, Lin.,...&Zhang, Tao.(2019).Production of 1,2-Cyclohexanedicarboxylates from Diacetone Alcohol and Fumarates.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(3),2980-2988.
MLA	Liang, Xinmiao,et al."Production of 1,2-Cyclohexanedicarboxylates from Diacetone Alcohol and Fumarates".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.3(2019):2980-2988.