Acid-base synergistic catalysis of biochar sulfonic acid bearing polyamide for microwave-assisted hydrolysis of cellulose in water

doi:10.1007/s10570-018-2098-3

	Acid-base synergistic catalysis of biochar sulfonic acid bearing polyamide for microwave-assisted hydrolysis of cellulose in water
	Yin, Dulin 2,3; Chen, Zengtian 2,3; Li, Qingfeng 2,3; Xiao, Yuxue 2,3; Zhang, Chao 2,3; Fu, Zaihui 2,3; Liu, Yachun 2,3; Yi, Xianfeng 1; Zheng, Anmin 1; Li, Changzhi 4
刊名	CELLULOSE
	2019
卷号	26 期号:2 页码:751-762
关键词	5-Hydroxymethylfurfural Biochar sulfonic acid Synergistic catalysis Cellulose hydrolysis Polyamide
ISSN号	0969-0239
DOI	10.1007/s10570-018-2098-3
通讯作者	Zhang, Chao(chaozhang2006@126.con) ; Fu, Zaihui(fzhhnnu@126.com)
英文摘要	The development of a highly efficient heterogeneous catalysis process for the hydrolysis of cellulose to reducing sugars (RSs) and especially 5-hydroxymethylfurfural (HMF) in water is highly anticipated for large-scale use of cellulosic biomass in the future. Herein, a bamboo-derived biochar sulfonic acid bearing polyamide (BCSA-PA) designed by us was found to show much higher catalytic activity, better repeatability and especially HMF yield for microwave-assisted such hydrolysis compared to the PA-free BCSA, achieving 25.60% RSs and 23.10% HMF yields with 4.71 turnover number (TON) under optimal conditions. Also, its TON value (2.58) for the conversion of cellulose into HMF was much higher than those obtained from it-catalyzed transformation of glucose (TON, 1.44) and especially fructose (TON, 0.79). The BCSA-PA showing an excellent catalysis performance in cellulose hydrolysis is likely due to the following two reasons: (1) the BCSA and especially BCSA-PA, as supported by glucose and cellobiose adsorption experiments, have a stronger affinity to -1,4-glycosidic bonds of cellulose than two monosaccharides, thereby leading to the highly-efficient hydrolysis of cellulose on the SO3H groups. (2) The acid-base synergistic catalysis between the SO3H and PA groups of BCSA-PA may be responsible for its higher HMF selectivity and excellent repeatability in water medium. The current work highlights new opportunities for the direct production of 5-HMF from glucose and especially cellulose. [GRAPHICS] .
资助项目	National Natural Science Fund of China[21676079] ; National Natural Science Fund of China[21546010] ; National Natural Science Fund of China[20873040] ; Specialized Research Fund for the Doctoral Program of Higher Education[20124306110005] ; Natural Science Fund of Hunan Province[2018JJ3335] ; Natural Science Fund of Hunan Province[14JJ2148] ; Natural Science Fund of Hunan Province[10JJ2007] ; Innovation Platform Open Fund of Hunan College[11K044] ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; 100 Talents Program of Hunan Province
WOS关键词	LIGNOCELLULOSIC BIOMASS ; IONIC LIQUID ; BIOMIMETIC CATALYST ; SOLID ACID ; CONVERSION ; GLUCOSE ; FRUCTOSE ; TRANSFORMATION ; CHEMICALS ; BAMBOO
WOS研究方向	Materials Science ; Polymer Science
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000459455200007
资助机构	National Natural Science Fund of China ; National Natural Science Fund of China ; Specialized Research Fund for the Doctoral Program of Higher Education ; Specialized Research Fund for the Doctoral Program of Higher Education ; Natural Science Fund of Hunan Province ; Natural Science Fund of Hunan Province ; Innovation Platform Open Fund of Hunan College ; Innovation Platform Open Fund of Hunan College ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; 100 Talents Program of Hunan Province ; 100 Talents Program of Hunan Province ; National Natural Science Fund of China ; National Natural Science Fund of China ; Specialized Research Fund for the Doctoral Program of Higher Education ; Specialized Research Fund for the Doctoral Program of Higher Education ; Natural Science Fund of Hunan Province ; Natural Science Fund of Hunan Province ; Innovation Platform Open Fund of Hunan College ; Innovation Platform Open Fund of Hunan College ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; 100 Talents Program of Hunan Province ; 100 Talents Program of Hunan Province ; National Natural Science Fund of China ; National Natural Science Fund of China ; Specialized Research Fund for the Doctoral Program of Higher Education ; Specialized Research Fund for the Doctoral Program of Higher Education ; Natural Science Fund of Hunan Province ; Natural Science Fund of Hunan Province ; Innovation Platform Open Fund of Hunan College ; Innovation Platform Open Fund of Hunan College ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; 100 Talents Program of Hunan Province ; 100 Talents Program of Hunan Province ; National Natural Science Fund of China ; National Natural Science Fund of China ; Specialized Research Fund for the Doctoral Program of Higher Education ; Specialized Research Fund for the Doctoral Program of Higher Education ; Natural Science Fund of Hunan Province ; Natural Science Fund of Hunan Province ; Innovation Platform Open Fund of Hunan College ; Innovation Platform Open Fund of Hunan College ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; 100 Talents Program of Hunan Province ; 100 Talents Program of Hunan Province
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/165938]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zhang, Chao; Fu, Zaihui
作者单位	1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Hubei, Peoples R China 2.Hunan Normal Univ, Natl & Local United Engn Lab New Petrochem Mat &, Key Lab Resource Fine Proc & Adv Mat Hunan Prov, Coll Chem & Chem Engn,Minist Educ China, Changsha 410081, Hunan, Peoples R China 3.Hunan Normal Univ, Coll Chem & Chem Engn, Minist Educ China, Key Lab Chem Biol & Tradit Chinese Med Res, Changsha 410081, Hunan, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Yin, Dulin,Chen, Zengtian,Li, Qingfeng,et al. Acid-base synergistic catalysis of biochar sulfonic acid bearing polyamide for microwave-assisted hydrolysis of cellulose in water[J]. CELLULOSE,2019,26(2):751-762.
APA	Yin, Dulin.,Chen, Zengtian.,Li, Qingfeng.,Xiao, Yuxue.,Zhang, Chao.,...&Li, Changzhi.(2019).Acid-base synergistic catalysis of biochar sulfonic acid bearing polyamide for microwave-assisted hydrolysis of cellulose in water.CELLULOSE,26(2),751-762.
MLA	Yin, Dulin,et al."Acid-base synergistic catalysis of biochar sulfonic acid bearing polyamide for microwave-assisted hydrolysis of cellulose in water".CELLULOSE 26.2(2019):751-762.