One-pot synthesis and self-assembly of colloidal copper(i) sulfide nanocrystals | |
Tang, Aiwei1,2; Qu, Shengchun1; Li, Kai3; Hou, Yanbing2; Teng, Feng2; Cao, Jie1; Wang, Yongsheng2; Wang, Zhanguo1 | |
刊名 | Nanotechnology |
2010-07-16 | |
卷号 | 21期号:28页码:9 |
ISSN号 | 0957-4484 |
DOI | 10.1088/0957-4484/21/28/285602 |
通讯作者 | Qu, shengchun(qsc@semi.ac.cn) |
英文摘要 | A simple one-pot method is developed to prepare size-and shape-controlled copper(i) sulfide (cu(2)s) nanocrystals by thermolysis of a mixed solution of copper acetylacetonate, dodecanethiol and oleylamine at a relatively high temperature. the crystal structure, chemical composition and morphology of the as-obtained products are characterized by powder x-ray diffraction (pxrd), x-ray photoelectron spectroscopy (xps), auger electron spectroscopy (aes), transmission electron microscopy (tem) and scanning electron microscopy (sem). the morphology and size of the cu(2)s nanocrystals can be easily controlled by adjusting the reaction parameters. the cu(2)s nanocrystals evolve from spherical to disk-like with increasing reaction temperature. the spherical cu(2)s nanocrystals have a high tendency to self-assemble into close-packed superlattice structures. the shape of the cu(2)s nanodisks changes from cylinder to hexagonal prism with prolonged reaction time, accompanied by the diameter and thickness increasing. more interestingly, the nanodisks are inclined to self-assemble into face-to-face stacking chains with different lengths and orientations. this one-pot approach may extend to synthesis of other metal sulfide nanocrystals with different shapes and sizes. |
WOS关键词 | BINARY NANOPARTICLE SUPERLATTICES ; LIGHT-EMITTING-DIODES ; SOLVENTLESS SYNTHESIS ; CDSE NANOCRYSTALS ; QUANTUM DOTS ; MONODISPERSE NANOCRYSTALS ; OPTICAL-PROPERTIES ; CDTE NANOCRYSTALS ; CU2S NANOCRYSTALS ; SOLAR-CELLS |
WOS研究方向 | Science & Technology - Other Topics ; Materials Science ; Physics |
WOS类目 | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
语种 | 英语 |
出版者 | IOP PUBLISHING LTD |
WOS记录号 | WOS:000279259100024 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2428017 |
专题 | 半导体研究所 |
通讯作者 | Qu, Shengchun |
作者单位 | 1.Chinese Acad Sci, Key Lab Semicond Mat Sci, Inst Semicond, Beijing 100083, Peoples R China 2.Beijing JiaoTong Univ, Key Lab Luminescence & Opt Informat, Minist Educ, Inst Optoelect Technol, Beijing 100044, Peoples R China 3.Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China |
推荐引用方式 GB/T 7714 | Tang, Aiwei,Qu, Shengchun,Li, Kai,et al. One-pot synthesis and self-assembly of colloidal copper(i) sulfide nanocrystals[J]. Nanotechnology,2010,21(28):9. |
APA | Tang, Aiwei.,Qu, Shengchun.,Li, Kai.,Hou, Yanbing.,Teng, Feng.,...&Wang, Zhanguo.(2010).One-pot synthesis and self-assembly of colloidal copper(i) sulfide nanocrystals.Nanotechnology,21(28),9. |
MLA | Tang, Aiwei,et al."One-pot synthesis and self-assembly of colloidal copper(i) sulfide nanocrystals".Nanotechnology 21.28(2010):9. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论