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One-pot synthesis and self-assembly of colloidal copper(i) sulfide nanocrystals
Tang, Aiwei1,2; Qu, Shengchun1; Li, Kai3; Hou, Yanbing2; Teng, Feng2; Cao, Jie1; Wang, Yongsheng2; Wang, Zhanguo1
刊名Nanotechnology
2010-07-16
卷号21期号:28页码:9
ISSN号0957-4484
DOI10.1088/0957-4484/21/28/285602
通讯作者Qu, shengchun(qsc@semi.ac.cn)
英文摘要A simple one-pot method is developed to prepare size-and shape-controlled copper(i) sulfide (cu(2)s) nanocrystals by thermolysis of a mixed solution of copper acetylacetonate, dodecanethiol and oleylamine at a relatively high temperature. the crystal structure, chemical composition and morphology of the as-obtained products are characterized by powder x-ray diffraction (pxrd), x-ray photoelectron spectroscopy (xps), auger electron spectroscopy (aes), transmission electron microscopy (tem) and scanning electron microscopy (sem). the morphology and size of the cu(2)s nanocrystals can be easily controlled by adjusting the reaction parameters. the cu(2)s nanocrystals evolve from spherical to disk-like with increasing reaction temperature. the spherical cu(2)s nanocrystals have a high tendency to self-assemble into close-packed superlattice structures. the shape of the cu(2)s nanodisks changes from cylinder to hexagonal prism with prolonged reaction time, accompanied by the diameter and thickness increasing. more interestingly, the nanodisks are inclined to self-assemble into face-to-face stacking chains with different lengths and orientations. this one-pot approach may extend to synthesis of other metal sulfide nanocrystals with different shapes and sizes.
WOS关键词BINARY NANOPARTICLE SUPERLATTICES ; LIGHT-EMITTING-DIODES ; SOLVENTLESS SYNTHESIS ; CDSE NANOCRYSTALS ; QUANTUM DOTS ; MONODISPERSE NANOCRYSTALS ; OPTICAL-PROPERTIES ; CDTE NANOCRYSTALS ; CU2S NANOCRYSTALS ; SOLAR-CELLS
WOS研究方向Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
语种英语
出版者IOP PUBLISHING LTD
WOS记录号WOS:000279259100024
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2428017
专题半导体研究所
通讯作者Qu, Shengchun
作者单位1.Chinese Acad Sci, Key Lab Semicond Mat Sci, Inst Semicond, Beijing 100083, Peoples R China
2.Beijing JiaoTong Univ, Key Lab Luminescence & Opt Informat, Minist Educ, Inst Optoelect Technol, Beijing 100044, Peoples R China
3.Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China
推荐引用方式
GB/T 7714
Tang, Aiwei,Qu, Shengchun,Li, Kai,et al. One-pot synthesis and self-assembly of colloidal copper(i) sulfide nanocrystals[J]. Nanotechnology,2010,21(28):9.
APA Tang, Aiwei.,Qu, Shengchun.,Li, Kai.,Hou, Yanbing.,Teng, Feng.,...&Wang, Zhanguo.(2010).One-pot synthesis and self-assembly of colloidal copper(i) sulfide nanocrystals.Nanotechnology,21(28),9.
MLA Tang, Aiwei,et al."One-pot synthesis and self-assembly of colloidal copper(i) sulfide nanocrystals".Nanotechnology 21.28(2010):9.
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