| Growth and properties of single crystals of noncentrosymmetric na3vo2b6o11 | |
| Fan, Xiaoyun1,2; Pan, Shilie1; Hou, Xueling1; Tian, Xuelin1; Han, Jian1; Haag, Jacob3; Poeppelmeier, Kenneth R.3 | |
| 刊名 | Crystal growth & design
 |
| 2010 | |
| 卷号 | 10期号:1页码:252-256 |
| ISSN号 | 1528-7483 |
| DOI | 10.1021/cg900877h |
| 通讯作者 | Pan, shilie(slpan@ms.xjb.ac.cn) |
| 英文摘要 | A new nonlinear optical crystal, na3vo2b6o11, hit s been grown by the top-seeded sol lit ion growl h method using it na2co3v2o5 flux. the structure of the compound was determined by single-crystal x-ray diffraction. it crystallizes in the noncentrosymmetric orthorhombic system, space group p2(1)2(1)2(1), with cell parameters a = 7.7359(9) angstrom, h = 10. 1884(12) angstrom, c = 12.5697(15) angstrom, v = 990.7(2) angstrom(3), and z = 4. na3vo2b6o11 has, a three-dimensional structure consisting of hexaborate groups connected by vo4 tetrahedra with the sodium atoms distributed in channels through out the three-dimensional network. the refractive indices have been measured by the minimum deviation technique and fit to the sellmeier equations. nonlinearoptical measurements on the compound demonstrate that the material has second harmonic generation properties, with an efficiency approximately the same as that of kh2bo4. |
| WOS关键词 | NONLINEAR-OPTICAL CRYSTAL ; BOND-VALENCE PARAMETERS ; NLO PROPERTIES ; CATIONS ; GENERATION ; KTIOPO4 ; SOLIDS ; CHEMISTRY ; COMPOUND ; CSB3O5 |
| WOS研究方向 | Chemistry ; Crystallography ; Materials Science |
| WOS类目 | Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000274757100040 |
| 内容类型 | 期刊论文 |
| URI标识 | http://www.corc.org.cn/handle/1471x/2413381 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Pan, Shilie |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Northwestern Univ, Dept Chem, Evanston, IL 60208 USA |
| 推荐引用方式 GB/T 7714 | Fan, Xiaoyun,Pan, Shilie,Hou, Xueling,et al. Growth and properties of single crystals of noncentrosymmetric na3vo2b6o11[J]. Crystal growth & design,2010,10(1):252-256. |
| APA | Fan, Xiaoyun.,Pan, Shilie.,Hou, Xueling.,Tian, Xuelin.,Han, Jian.,...&Poeppelmeier, Kenneth R..(2010).Growth and properties of single crystals of noncentrosymmetric na3vo2b6o11.Crystal growth & design,10(1),252-256. |
| MLA | Fan, Xiaoyun,et al."Growth and properties of single crystals of noncentrosymmetric na3vo2b6o11".Crystal growth & design 10.1(2010):252-256. |
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