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	Rhodium(ii) catalyzed multi-component reactions of aryldiazoacetates with titanium(iv) isopropoxide and imines
	Zhang, Xu1,2,3; Zhang, Na1; Guo, Xin1; Yang, Liping1; Hu, Wenhao1
刊名	Tetrahedron
	2009-09-26
卷号	65期号:39页码:8277-8282
关键词	Oxonium ylide Multi-component reaction Aryldiazoacetate Titanium(iv) isopropoxide
ISSN号	0040-4020
DOI	10.1016/j.tet.2009.07.049
通讯作者	Hu, wenhao()
英文摘要	Rh(2)(oac)(4) catalyzed diazo decomposition of aryldiazoacetates in the presence of titanium(iv) isopropoxide generated oxonium ylide intermediates trapping of the oxonium ylide intermediates with imines occurred subsequently via a nucleophilic addition the three-component reaction of aryldiazoacetates, titanium(iv) isopropoxide, and imines gave alpha-alkoxyl-beta-amino acid derivatives with c-n/c-c bond formation in a single step. extension of the study to a four-component reaction with in situ generated imine was also investigated (c) 2009 elsevier ltd. all rights reserved
WOS关键词	CARBON BOND FORMATION ; H INSERTION REACTIONS ; LOW-VALENT TITANIUM ; OXONIUM YLIDE ; STEREOSELECTIVE SYNTHESIS ; ASYMMETRIC EPOXIDATION ; 3-COMPONENT REACTIONS ; ORGANIC-SYNTHESIS ; METAL-COMPLEXES ; CYCLOPROPANATION
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000270121400028
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2405375
专题	中国科学院大学
通讯作者	Hu, Wenhao
作者单位	1.E China Normal Univ, Dept Chem, Shanghai 20062, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Xu,Zhang, Na,Guo, Xin,et al. Rhodium(ii) catalyzed multi-component reactions of aryldiazoacetates with titanium(iv) isopropoxide and imines[J]. Tetrahedron,2009,65(39):8277-8282.
APA	Zhang, Xu,Zhang, Na,Guo, Xin,Yang, Liping,&Hu, Wenhao.(2009).Rhodium(ii) catalyzed multi-component reactions of aryldiazoacetates with titanium(iv) isopropoxide and imines.Tetrahedron,65(39),8277-8282.
MLA	Zhang, Xu,et al."Rhodium(ii) catalyzed multi-component reactions of aryldiazoacetates with titanium(iv) isopropoxide and imines".Tetrahedron 65.39(2009):8277-8282.

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