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Effects of metal catalysts on co2 gasification reactivity of biomass char
Huang, Yanqin1,2; Yin, Xiuli1; Wu, Chuangzhi1; Wang, Congwei1; Xie, Jianjun1; Zhou, Zhaoqiu1; Ma, Longlong1; Li, Haibin1
刊名Biotechnology advances
2009-09-01
卷号27期号:5页码:568-572
关键词Fir chars Co2 gasification Metal catalysts Xrd Sem Kinetic parameters
ISSN号0734-9750
DOI10.1016/j.biotechadv.2009.04.013
通讯作者Yin, xiuli(xlyin@ms.giec.ac.cn)
英文摘要The effects of five metal catalysts (k, na, ca, mg, and fe) on co2 gasification reactivity of fir char were studied using thermal gravimetric analysis. the degree of carbonization, crystal structure and morphology of char samples was characterized by x-ray diffractometry (xrd) and scanning electron microscopy (sem). the co2 gasification reactivity of fir char was improved through the addition of metal catalysts, in the order k>na>ca>fe>mg. xrd analysis indicated that na and ca improved the formation of crystal structure and that, mg enhanced the degree of carbon structure ordering. sem analysis showed that spotted activation centers were distributed on the surface of char samples impregnated with catalysts. moreover, a loose flake structure was observed on the surface of both k-char and na-char. finally, the kinetic parameters of co2 gasification of char samples were calculated mathematically. (c) 2009 elsevier inc. all rights reserved.
WOS关键词COAL ; CARBON ; GASIFIER ; GAS
WOS研究方向Biotechnology & Applied Microbiology
WOS类目Biotechnology & Applied Microbiology
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000267741300006
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2404400
专题中国科学院大学
通讯作者Yin, Xiuli
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Renewable Energy & Gas Hydrate Key Lab, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Huang, Yanqin,Yin, Xiuli,Wu, Chuangzhi,et al. Effects of metal catalysts on co2 gasification reactivity of biomass char[J]. Biotechnology advances,2009,27(5):568-572.
APA Huang, Yanqin.,Yin, Xiuli.,Wu, Chuangzhi.,Wang, Congwei.,Xie, Jianjun.,...&Li, Haibin.(2009).Effects of metal catalysts on co2 gasification reactivity of biomass char.Biotechnology advances,27(5),568-572.
MLA Huang, Yanqin,et al."Effects of metal catalysts on co2 gasification reactivity of biomass char".Biotechnology advances 27.5(2009):568-572.
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