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Facile fabrication of raspberry-like composite nanoparticles and their application as building blocks for constructing superhydrophilic coatings
Du, Xin1,2,3; Liu, Xiangmei1,2,3; Chen, Hongmin1,2,3; He, Junhui1,2
刊名Journal of physical chemistry c
2009-05-28
卷号113期号:21页码:9063-9070
ISSN号1932-7447
DOI10.1021/jp9016344
通讯作者He, junhui(jhhe@mail.ipc.ac.cn)
英文摘要Monodisperse raspberry-like polystyrene@silica composite nanoparticles (rcns) were readily prepared by a single-step sol-gel method, using oxygen plasma-treated monodisperse polystyrene (ps) spheres as cores. the fabricated composite particles have a well-defined structure and a surface morphology of dual-size roughness. the diameter of silica nanoparticles and their coverage degree on the surface of ps spheres could be easily tailored by adjusting the tetraethoxysilane concentration. subsequently, porous silica hollow sphere coatings were fabricated by depositing the rcns on polyelectrolyte-modified glass substrates via layer-by-layer assembly followed by calcination. such porous silica hollow sphere coatings present unique superhydrophilic and antifogging properties even though the coverage degree of porous silica hollow spheres on substrates is only ca. 50%. therefore, the obtained raspberry-like composite spheres are ideal building blocks for constructing superhydrophilic and superhydrophobic coatings.
WOS关键词HOLLOW SILICA SPHERES ; BY-LAYER DEPOSITION ; EMULSION POLYMERIZATION ; ANTIFOGGING COATINGS ; POLYSTYRENE ; PARTICLES ; SURFACES ; PLASMA ; FILMS ; POSTCALCINATION
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000266390100009
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2404382
专题中国科学院大学
通讯作者He, Junhui
作者单位1.Chinese Acad Sci, Funct Nanomat Lab, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Key Lab Photochem Convers & Optoelect Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Du, Xin,Liu, Xiangmei,Chen, Hongmin,et al. Facile fabrication of raspberry-like composite nanoparticles and their application as building blocks for constructing superhydrophilic coatings[J]. Journal of physical chemistry c,2009,113(21):9063-9070.
APA Du, Xin,Liu, Xiangmei,Chen, Hongmin,&He, Junhui.(2009).Facile fabrication of raspberry-like composite nanoparticles and their application as building blocks for constructing superhydrophilic coatings.Journal of physical chemistry c,113(21),9063-9070.
MLA Du, Xin,et al."Facile fabrication of raspberry-like composite nanoparticles and their application as building blocks for constructing superhydrophilic coatings".Journal of physical chemistry c 113.21(2009):9063-9070.
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