QQ客服 官方微博 反馈留言

	Synthesis, structures, and spectroscopic properties of copper(i) complexes bearing 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine and 1,2-bis(diphenylphosphino)ethane ligands
	Chi, Shao-Ming1; Wang, Yu-Fei2; Gan, Xin2; Wang, De-Hui2; Fu, Wen-1,2
刊名	Central european journal of chemistry
	2009-12-01
卷号	7期号:4页码:923-928
关键词	Copper(i) complex Phosphine ligand Napaa Crystal structure Photophysical properties
ISSN号	1895-1066
DOI	10.2478/s11532-009-0087-y
通讯作者	Chi, shao-ming()
英文摘要	A new ligand napaa (napaa = 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine) and its two dinuclear copper(i) complexes, cu(2)(napaa)(dppe)(2)(clo(4))(2) (1) and cu(2)(napaa)(pph(3))(4)(bf(4))(2) (2) (dppe = 1,2-bis(diphenylphosphino)ethane) and pph(3) = triphenylphosphine) were synthesized and characterized, and the structure of 1 was determined by x-ray crystal analysis. each copper atom in 1 has a distorted tetrahedral geometry in which the metal center is associated to napaa and dppe ligands displaying chelating coordination modes and the naphthyridine rings of napaa are almost coplanar. the two complexes exhibit similar electronic absorption spectra with lambda(max) at about 366 nm, which can be tentatively assigned to metal-to-ligand charge-transfer (mlct) transition. the assignment was further supported by density functional theory (dft) calculations.
WOS关键词	CRYSTAL-STRUCTURE ; 1,8-NAPHTHYRIDINE ; CU2+
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	VERSITA
WOS记录号	WOS:000270541000033
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2400324
专题	中国科学院大学
通讯作者	Chi, Shao-Ming
作者单位	1.Chinese Acad Sci, Grad Univ, Tech Inst Phys & Chem, Beijing 100190, Peoples R China 2.Yunnan Normal Univ, Coll Chem & Chem Engn, Kunming 650092, Peoples R China
推荐引用方式 GB/T 7714	Chi, Shao-Ming,Wang, Yu-Fei,Gan, Xin,et al. Synthesis, structures, and spectroscopic properties of copper(i) complexes bearing 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine and 1,2-bis(diphenylphosphino)ethane ligands[J]. Central european journal of chemistry,2009,7(4):923-928.
APA	Chi, Shao-Ming,Wang, Yu-Fei,Gan, Xin,Wang, De-Hui,&Fu, Wen-.(2009).Synthesis, structures, and spectroscopic properties of copper(i) complexes bearing 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine and 1,2-bis(diphenylphosphino)ethane ligands.Central european journal of chemistry,7(4),923-928.
MLA	Chi, Shao-Ming,et al."Synthesis, structures, and spectroscopic properties of copper(i) complexes bearing 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine and 1,2-bis(diphenylphosphino)ethane ligands".Central european journal of chemistry 7.4(2009):923-928.

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。