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	The palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions
	Tang, Cong-Ming1,2,3,4; Zeng, Yi1; Yang, Xian-Gui1; Lei, Yong-Cheng1; Wang, Gong-Ying1,3
刊名	Journal of molecular catalysis a-chemical
	2009-12-01
卷号	314期号:1-2页码:15-20
关键词	Acrylic acid Palladium acetate Diphenyl-2-pyridylphosphine Trifluoromethane sulfonic acid Hydrocarboxylation Acetylene Carbon monoxide
ISSN号	1381-1169
DOI	10.1016/j.molcata.2009.08.008
通讯作者	Wang, gong-ying()
英文摘要	Hydrocarboxylation of acetylene with carbon monoxide to acrylic acid has been carried out using a catalyst system consisting of pd(oac)(2). phosphine ligands and acids under the mild conditions. the effects of acidic promoters, phosphine ligands, water. reaction time and the initial partial pressure of carbon monoxide oil the conversion of acetylene as well as the selectivity to acrylic acid have been investigated among all ligands as used, only diphenyl-2-pyridylphosphine has a good catalytic activity. sulfonic acids and trifluoroacetic acid as acidic promoters display an excellent performance. effects of water and the initial partial pressure of carbon monoxide have also been discussed. under the optimal reaction conditions, 85% conversion of acetylene and 99% selectivity to acrylic acid as well as 1011 h(-1) tof have been achieved. crown copyright (c) 2009 published by elsevier b v all rights reserved.
WOS关键词	COMPLEX CATALYST ; REPPE CARBONYLATION ; HYDROESTERIFICATION ; ALKYNES ; PRESSURE ; CARBOXYLATION ; PHOSPHINES ; WATER
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000272114300003
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2394018
专题	中国科学院大学
通讯作者	Wang, Gong-Ying
作者单位	1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.China W Normal Univ, Coll Chem & Chem Engn, Nanchong 637002, Sichuan, Peoples R China 3.Changzhou Inst Chem, Changzhou 213164, Jiangshu, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing 10049, Peoples R China
推荐引用方式 GB/T 7714	Tang, Cong-Ming,Zeng, Yi,Yang, Xian-Gui,et al. The palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions[J]. Journal of molecular catalysis a-chemical,2009,314(1-2):15-20.
APA	Tang, Cong-Ming,Zeng, Yi,Yang, Xian-Gui,Lei, Yong-Cheng,&Wang, Gong-Ying.(2009).The palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions.Journal of molecular catalysis a-chemical,314(1-2),15-20.
MLA	Tang, Cong-Ming,et al."The palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions".Journal of molecular catalysis a-chemical 314.1-2(2009):15-20.

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