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	Effect of reactive group types on the properties of core-shell modifiers toughened pa6
	Sun, Shulin1; Chen, Zhicheng1; Zhang, Huixun1,2
刊名	Polymer bulletin
	2008-10-01
卷号	61期号:4页码:443-452
ISSN号	0170-0839
DOI	10.1007/s00289-008-0971-1
通讯作者	Zhang, huixun(ssl@mail.ccut.edu.cn)
英文摘要	Reactive monomers such as acrylic acid (aa), maleic anhydride (ma) and glycidyl methacrylate (gma) were grafted onto acrylonitrile-butadiene-styrene core-shell copolymer (abs) by emulsion polymerization method. these functionalized abs were used to toughen pa6. ftir and molau tests showed that these monomers were introduced onto abs copolymers and compatibilization reactions took place between pa6 and the aa, ma and gma grafted abs. tem result showed that the modified abs copolymer dispersed in pa6 matrix uniformly and no obvious difference could be found between the different pa6 blends. however, mechanical test showed that gma and ma modified abs achieved much better toughening effect than the aa grafted abs copolymer due to the stronger interfacial reactions. fracture characterization indicated that pa6 toughened with gma and ma modified abs showed higher g(i)values according to the vu-khanh approach and much obvious shear yielding in the deformed zone could be found.
WOS关键词	NYLON 6/ABS BLENDS ; FRACTURE-BEHAVIOR ; POLYMER BLENDS ; ABS BLENDS ; COMPATIBILIZER ; MORPHOLOGY ; TEMPERATURE ; POLYAMIDE-6 ; COPOLYMERS
WOS研究方向	Polymer Science
WOS类目	Polymer Science
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000259257400005
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2387481
专题	中国科学院大学
通讯作者	Zhang, Huixun
作者单位	1.Changchun Univ Technol, Sch Chem Engn, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Sun, Shulin,Chen, Zhicheng,Zhang, Huixun. Effect of reactive group types on the properties of core-shell modifiers toughened pa6[J]. Polymer bulletin,2008,61(4):443-452.
APA	Sun, Shulin,Chen, Zhicheng,&Zhang, Huixun.(2008).Effect of reactive group types on the properties of core-shell modifiers toughened pa6.Polymer bulletin,61(4),443-452.
MLA	Sun, Shulin,et al."Effect of reactive group types on the properties of core-shell modifiers toughened pa6".Polymer bulletin 61.4(2008):443-452.

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