Effect of kcl on selective catalytic reduction of no with nh3 over av(2)o(5)/ac catalyst | |
Zhang, Xianlong2,3; Huang, Zhanggen3; Liu, Zhenyu1,3 | |
刊名 | Catalysis communications |
2008-03-20 | |
卷号 | 9期号:5页码:842-846 |
关键词 | V2o5/ac catalyst Low temperature scr Deactivation Kcl |
ISSN号 | 1566-7367 |
DOI | 10.1016/j.catcom.2007.09.008 |
通讯作者 | Liu, zhenyu(zyliu@sxicc.ac.cn) |
英文摘要 | Deactivation of a low temperature selective catalytic reduction (scr) catalyst, 1 wt% v2o5/ac, by potassium chloride (kcl) is studied using bet and pore size distribution measurements, nh3 sorption and temperature-programmed desorption (tpd), temperature-programmed surface reaction (tpsr). results show that kcl deactivates 1 wt%v2o5/ac's scr activity and the deactivation become severer at higher kcl loadings. the deactivation is not caused by pore plugging but by neutralization of acid sites on v2o5/ac. weak acid sites are responsible for nh3 activation and scr of no, and are preferentially deactivated by kcl. (c) 2007 elsevier b.v. all rights reserved. |
WOS关键词 | FLUIDIZED-BED COMBUSTION ; SCR CATALYSTS ; NITRIC-OXIDE ; ASH BEHAVIOR ; AMMONIA ; BIOMASS ; DEACTIVATION ; TEMPERATURES ; SALTS ; SO2 |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000253450900053 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2386986 |
专题 | 中国科学院大学 |
通讯作者 | Liu, Zhenyu |
作者单位 | 1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Xianlong,Huang, Zhanggen,Liu, Zhenyu. Effect of kcl on selective catalytic reduction of no with nh3 over av(2)o(5)/ac catalyst[J]. Catalysis communications,2008,9(5):842-846. |
APA | Zhang, Xianlong,Huang, Zhanggen,&Liu, Zhenyu.(2008).Effect of kcl on selective catalytic reduction of no with nh3 over av(2)o(5)/ac catalyst.Catalysis communications,9(5),842-846. |
MLA | Zhang, Xianlong,et al."Effect of kcl on selective catalytic reduction of no with nh3 over av(2)o(5)/ac catalyst".Catalysis communications 9.5(2008):842-846. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论