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Effect of kcl on selective catalytic reduction of no with nh3 over av(2)o(5)/ac catalyst
Zhang, Xianlong2,3; Huang, Zhanggen3; Liu, Zhenyu1,3
刊名Catalysis communications
2008-03-20
卷号9期号:5页码:842-846
关键词V2o5/ac catalyst Low temperature scr Deactivation Kcl
ISSN号1566-7367
DOI10.1016/j.catcom.2007.09.008
通讯作者Liu, zhenyu(zyliu@sxicc.ac.cn)
英文摘要Deactivation of a low temperature selective catalytic reduction (scr) catalyst, 1 wt% v2o5/ac, by potassium chloride (kcl) is studied using bet and pore size distribution measurements, nh3 sorption and temperature-programmed desorption (tpd), temperature-programmed surface reaction (tpsr). results show that kcl deactivates 1 wt%v2o5/ac's scr activity and the deactivation become severer at higher kcl loadings. the deactivation is not caused by pore plugging but by neutralization of acid sites on v2o5/ac. weak acid sites are responsible for nh3 activation and scr of no, and are preferentially deactivated by kcl. (c) 2007 elsevier b.v. all rights reserved.
WOS关键词FLUIDIZED-BED COMBUSTION ; SCR CATALYSTS ; NITRIC-OXIDE ; ASH BEHAVIOR ; AMMONIA ; BIOMASS ; DEACTIVATION ; TEMPERATURES ; SALTS ; SO2
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000253450900053
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2386986
专题中国科学院大学
通讯作者Liu, Zhenyu
作者单位1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
3.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Xianlong,Huang, Zhanggen,Liu, Zhenyu. Effect of kcl on selective catalytic reduction of no with nh3 over av(2)o(5)/ac catalyst[J]. Catalysis communications,2008,9(5):842-846.
APA Zhang, Xianlong,Huang, Zhanggen,&Liu, Zhenyu.(2008).Effect of kcl on selective catalytic reduction of no with nh3 over av(2)o(5)/ac catalyst.Catalysis communications,9(5),842-846.
MLA Zhang, Xianlong,et al."Effect of kcl on selective catalytic reduction of no with nh3 over av(2)o(5)/ac catalyst".Catalysis communications 9.5(2008):842-846.
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