Effects of mg2+ on supported bilayer lipid membrane on a glassy carbon electrode during membrane formation | |
Zhang, Hongwei1; Zhang, Zhanjun1; Li, Jingjian2; Cai, Shengmin2 | |
刊名 | International journal of electrochemical science |
2007-10-01 | |
卷号 | 2期号:10页码:788-796 |
关键词 | Supported bilayer lipid membrane Mg2+ Cyclic voltammetry Electrochemical impedance spectroscopy |
ISSN号 | 1452-3981 |
通讯作者 | Zhang, hongwei() |
英文摘要 | The effects of mg2+ on supported bilayer lipid membrane (s-blm) during membrane formation were investigated by cyclic voltammetry (cv) and electrochemical impedance spectroscopy (eis). there was an increase of the peak-to-peak separation between the cathodic and anodic waves from cv, and an obvious decrease of charge transfer resistance from eis for the membrane formed in 0.1m mgcl2 compared with that in 0.1m kcl. the higher ionic strength of mgcl2 led to more lipid molecules dropping from the surface of the electrode before they were ready to be in directional arrangement to form s-blm, so the membrane was not so dense. when reducing the concentration of mgcl2 to 0.03m or 0.05m, the total resistance decreased during the scanning process, which suggested the structure of the lipid membrane changed. the interaction between mg2+ and hydrophilic parts of lipid molecules should be responsible for the phenomena. |
WOS关键词 | MAGNESIUM-IONS ; IMPEDANCE ; BIOSENSOR ; TRANSPORT ; CHANNELS ; BLM ; ATP |
WOS研究方向 | Electrochemistry |
WOS类目 | Electrochemistry |
语种 | 英语 |
出版者 | ELECTROCHEMICAL SCIENCE GROUP |
WOS记录号 | WOS:000256381700005 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2380317 |
专题 | 中国科学院大学 |
通讯作者 | Zhang, Hongwei |
作者单位 | 1.Chinese Acad Sci, Coll Chem & Chem Engn, Grad Univ, Beijing 100049, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Hongwei,Zhang, Zhanjun,Li, Jingjian,et al. Effects of mg2+ on supported bilayer lipid membrane on a glassy carbon electrode during membrane formation[J]. International journal of electrochemical science,2007,2(10):788-796. |
APA | Zhang, Hongwei,Zhang, Zhanjun,Li, Jingjian,&Cai, Shengmin.(2007).Effects of mg2+ on supported bilayer lipid membrane on a glassy carbon electrode during membrane formation.International journal of electrochemical science,2(10),788-796. |
MLA | Zhang, Hongwei,et al."Effects of mg2+ on supported bilayer lipid membrane on a glassy carbon electrode during membrane formation".International journal of electrochemical science 2.10(2007):788-796. |
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