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Effects of mg2+ on supported bilayer lipid membrane on a glassy carbon electrode during membrane formation
Zhang, Hongwei1; Zhang, Zhanjun1; Li, Jingjian2; Cai, Shengmin2
刊名International journal of electrochemical science
2007-10-01
卷号2期号:10页码:788-796
关键词Supported bilayer lipid membrane Mg2+ Cyclic voltammetry Electrochemical impedance spectroscopy
ISSN号1452-3981
通讯作者Zhang, hongwei()
英文摘要The effects of mg2+ on supported bilayer lipid membrane (s-blm) during membrane formation were investigated by cyclic voltammetry (cv) and electrochemical impedance spectroscopy (eis). there was an increase of the peak-to-peak separation between the cathodic and anodic waves from cv, and an obvious decrease of charge transfer resistance from eis for the membrane formed in 0.1m mgcl2 compared with that in 0.1m kcl. the higher ionic strength of mgcl2 led to more lipid molecules dropping from the surface of the electrode before they were ready to be in directional arrangement to form s-blm, so the membrane was not so dense. when reducing the concentration of mgcl2 to 0.03m or 0.05m, the total resistance decreased during the scanning process, which suggested the structure of the lipid membrane changed. the interaction between mg2+ and hydrophilic parts of lipid molecules should be responsible for the phenomena.
WOS关键词MAGNESIUM-IONS ; IMPEDANCE ; BIOSENSOR ; TRANSPORT ; CHANNELS ; BLM ; ATP
WOS研究方向Electrochemistry
WOS类目Electrochemistry
语种英语
出版者ELECTROCHEMICAL SCIENCE GROUP
WOS记录号WOS:000256381700005
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2380317
专题中国科学院大学
通讯作者Zhang, Hongwei
作者单位1.Chinese Acad Sci, Coll Chem & Chem Engn, Grad Univ, Beijing 100049, Peoples R China
2.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Hongwei,Zhang, Zhanjun,Li, Jingjian,et al. Effects of mg2+ on supported bilayer lipid membrane on a glassy carbon electrode during membrane formation[J]. International journal of electrochemical science,2007,2(10):788-796.
APA Zhang, Hongwei,Zhang, Zhanjun,Li, Jingjian,&Cai, Shengmin.(2007).Effects of mg2+ on supported bilayer lipid membrane on a glassy carbon electrode during membrane formation.International journal of electrochemical science,2(10),788-796.
MLA Zhang, Hongwei,et al."Effects of mg2+ on supported bilayer lipid membrane on a glassy carbon electrode during membrane formation".International journal of electrochemical science 2.10(2007):788-796.
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