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Adsorption properties of crosslinked carboxymethyl-chitosan resin with pb(ii) as template ions
Sun, Shengling; Wang, Li; Wang, Aiqin
刊名Journal of hazardous materials
2006-08-25
卷号136期号:3页码:930-937
关键词Adsorption N,o-carboxymethyl-chitosan Crosslinked Lead Template
ISSN号0304-3894
DOI10.1016/j.jazmat.2006.01.033
通讯作者Wang, aiqin(aqwang@lzb.ac.cn)
英文摘要In the current study, we attempt to find a new adsorbent material based on chitosan to improve adsorption selectivity for heavy metals, so that the crosslinked no-carboxymethyl-chitosan resin with pb(ii) as template ions (crosslinked cmc template) were synthesized by using cmc adsorbed pb(h) ions crosslinked with glutaraldehyde. the effects on adsorption capacities such as amount of crosslinking agent, degree of substitution of cmc, ph value of the initial solution and adsorption time were investigated. the adsorption experiments demonstrated the crosslinked cmc template has high adsorption selectivity for pb(ii) ions in solution containing single metal ions or coexistence of three metals ions of cu(ii), zn(ii) and pb(h). furthermore, it was investigated that the crosslinked cmc template has a good reusability and stability as compared to cnic. finally, we studied the adsorption mechanism by ftir spectra and xps analysis. the results reveal that the adsorption of crosslinked cmc template and cmc for pb(ii) is a chelation process. (c) 2006 elsevier b.v. all rights reserved.
WOS关键词REMOVAL ; WATER ; METAL ; EQUILIBRIUM
WOS研究方向Engineering ; Environmental Sciences & Ecology
WOS类目Engineering, Environmental ; Engineering, Civil ; Environmental Sciences
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000240209700070
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2379368
专题中国科学院大学
通讯作者Wang, Aiqin
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Sun, Shengling,Wang, Li,Wang, Aiqin. Adsorption properties of crosslinked carboxymethyl-chitosan resin with pb(ii) as template ions[J]. Journal of hazardous materials,2006,136(3):930-937.
APA Sun, Shengling,Wang, Li,&Wang, Aiqin.(2006).Adsorption properties of crosslinked carboxymethyl-chitosan resin with pb(ii) as template ions.Journal of hazardous materials,136(3),930-937.
MLA Sun, Shengling,et al."Adsorption properties of crosslinked carboxymethyl-chitosan resin with pb(ii) as template ions".Journal of hazardous materials 136.3(2006):930-937.
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