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The negative biodegradation of poly(vinyl alcohol) modified by aldehydes
Zhang, Hui Zhen; Liu, Bai Ling; Luo, Rong; Wu, Yongzhong; Lei, Desong
刊名Polymer degradation and stability
2006-08-01
卷号91期号:8页码:1740-1746
关键词Poly(vinyl alcohol) (pva) Biodegradation Pva-degrading microorganisms Spectrophotometric analysis Modification
ISSN号0141-3910
DOI10.1016/j.polymdegradstab.2005.11.019
通讯作者Liu, bai ling(blliuchem@hotmail.com)
英文摘要Due to the wide application of pva acetals, the biodegradation of pva modified by formaldehyde, n-butyraldehyde, glyoxaldehyde and glutaraldehyde was conducted in an intensive biodegradation environment. spectrophotometric analysis and weight loss were used to determine the biodegradation of pva, and the changes of the mechanical properties of pva acetals were also studied. an obvious decrease in biodegradation levels of all the modified samples was found, and a decrease in biodegradation level with increasing degree of acetals of pva. the biodegradation of poly(vinyl formal) is better than poly(vinyl butyral) with the same degree of acetals whereas the biodegradation levels of poly(vinyl glyoxal) are lower than poly(vinyl glutaral) which has the same degree of crosslinking. the difference between the ft-ir of the samples before and after biodegradation indicated scission of residual pva chain during the process. (c) 2005 elsevier ltd. all rights reserved.
WOS关键词POLYVINYL-ALCOHOL ; DEGRADING ENZYME ; PURIFICATION ; PSEUDOMONAS ; POLYMERS ; STRAIN
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000238455300014
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2378918
专题中国科学院大学
通讯作者Liu, Bai Ling
作者单位1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.SINOPEC, Res Inst Sichuan Vinylon Works, Chongqing 401254, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Hui Zhen,Liu, Bai Ling,Luo, Rong,et al. The negative biodegradation of poly(vinyl alcohol) modified by aldehydes[J]. Polymer degradation and stability,2006,91(8):1740-1746.
APA Zhang, Hui Zhen,Liu, Bai Ling,Luo, Rong,Wu, Yongzhong,&Lei, Desong.(2006).The negative biodegradation of poly(vinyl alcohol) modified by aldehydes.Polymer degradation and stability,91(8),1740-1746.
MLA Zhang, Hui Zhen,et al."The negative biodegradation of poly(vinyl alcohol) modified by aldehydes".Polymer degradation and stability 91.8(2006):1740-1746.
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