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	New class of conjugated polyacetylenes having perylene bisimide units and pendant fullerene or porphyrin groups
	Liu, Y; Wang, N; Li, YJ; Liu, HB; Li, YL; Xiao, JH; Xu, XH; Huang, CS; Cui, S; Zhu, DB
刊名	Macromolecules
	2005-05-31
卷号	38期号:11页码:4880-4887
ISSN号	0024-9297
DOI	10.1021/ma050434k
通讯作者	Li, yj()
英文摘要	A new class of conjugated polyacetylenes having perylene bisimide units and pendant fullerene or porphyrin groups were synthesized and characterized. sem images displayed the aggregation superstructures of two polymers. the poly(5(0.1)-co-4(0.9)) can form a large quantity of spherical nanoparticles in chloroform because [60]fullerene derivatives have high aggregation tendency due to the π-π* stacking of the carbon cage. furthermore, poly(6(0.1)-co-4(0.9)) can form different aggregation structures in chloroform with the addition of 4,4'-bipyridine (bipy). in particular, when poly(6(0.1)-co-4(0.9)) was mixed with 2 equiv of bipy, a uniform cottonlike superstructure was observed. these results indicated that the axial coordination of zinc porphyrin and bipy played an important role in controlling the aggregation morphologies of poly(6(0.1)-co-4(0.9)) in chcl3 with the addition of bipy. more interestingly, the photocurrent measurement showed that the films of these polyacetylenes could produce steady and rapid cathodic photocurrent responses, indicating that efficient charge transfer took place in two donor-acceptor polymers.
WOS关键词	PHOTOINDUCED ELECTRON-TRANSFER ; ENERGY-TRANSFER ; HIGHLY FLUORESCENT ; PHOTOVOLTAIC PROPERTIES ; NITROXIDE RADICALS ; OPTICAL-PROPERTIES ; MOLECULAR SQUARES ; HELICAL ARRAY ; DERIVATIVES ; DYES
WOS研究方向	Polymer Science
WOS类目	Polymer Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000229536200047
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2378383
专题	中国科学院大学
通讯作者	Li, YJ
作者单位	1.Chinese Acad Sci, Ctr Mol Sci, CAS Key Lab Organ Solids, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Liu, Y,Wang, N,Li, YJ,et al. New class of conjugated polyacetylenes having perylene bisimide units and pendant fullerene or porphyrin groups[J]. Macromolecules,2005,38(11):4880-4887.
APA	Liu, Y.,Wang, N.,Li, YJ.,Liu, HB.,Li, YL.,...&Zhu, DB.(2005).New class of conjugated polyacetylenes having perylene bisimide units and pendant fullerene or porphyrin groups.Macromolecules,38(11),4880-4887.
MLA	Liu, Y,et al."New class of conjugated polyacetylenes having perylene bisimide units and pendant fullerene or porphyrin groups".Macromolecules 38.11(2005):4880-4887.

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