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The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes
Lu, CD; Liu, H; Chen, ZY; Hu, WH; Mi, AQ
刊名Chemical communications
2005
期号20页码:2624-2626
ISSN号1359-7345
DOI10.1039/b502093j
通讯作者Hu, wh()
英文摘要The rhodium(ii)-catalyzed three-component reaction of diazoacetates, titanium alkoxides and aldehydes is shown to give alpha-alkoxyl-beta-hydroxyl acid derivatives; the novel c - c bond formation reaction is proposed to occur through oxonium ylides derived from diazo compounds and titanium alkoxides, and followed by intermolecular trapping by aldehydes.
WOS关键词METAL CARBENE TRANSFORMATIONS ; ACID ETHYL-ESTERS ; CARBONYL YLIDE ; AROMATIC-ALDEHYDES ; OXONIUM YLIDE ; CYCLOADDITION ; EPOXIDES
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000229160100029
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2377192
专题中国科学院大学
通讯作者Hu, WH
作者单位1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
推荐引用方式
GB/T 7714
Lu, CD,Liu, H,Chen, ZY,et al. The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes[J]. Chemical communications,2005(20):2624-2626.
APA Lu, CD,Liu, H,Chen, ZY,Hu, WH,&Mi, AQ.(2005).The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes.Chemical communications(20),2624-2626.
MLA Lu, CD,et al."The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes".Chemical communications .20(2005):2624-2626.
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