The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes | |
Lu, CD; Liu, H; Chen, ZY; Hu, WH; Mi, AQ | |
刊名 | Chemical communications |
2005 | |
期号 | 20页码:2624-2626 |
ISSN号 | 1359-7345 |
DOI | 10.1039/b502093j |
通讯作者 | Hu, wh() |
英文摘要 | The rhodium(ii)-catalyzed three-component reaction of diazoacetates, titanium alkoxides and aldehydes is shown to give alpha-alkoxyl-beta-hydroxyl acid derivatives; the novel c - c bond formation reaction is proposed to occur through oxonium ylides derived from diazo compounds and titanium alkoxides, and followed by intermolecular trapping by aldehydes. |
WOS关键词 | METAL CARBENE TRANSFORMATIONS ; ACID ETHYL-ESTERS ; CARBONYL YLIDE ; AROMATIC-ALDEHYDES ; OXONIUM YLIDE ; CYCLOADDITION ; EPOXIDES |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000229160100029 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2377192 |
专题 | 中国科学院大学 |
通讯作者 | Hu, WH |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China |
推荐引用方式 GB/T 7714 | Lu, CD,Liu, H,Chen, ZY,et al. The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes[J]. Chemical communications,2005(20):2624-2626. |
APA | Lu, CD,Liu, H,Chen, ZY,Hu, WH,&Mi, AQ.(2005).The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes.Chemical communications(20),2624-2626. |
MLA | Lu, CD,et al."The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes".Chemical communications .20(2005):2624-2626. |
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