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Synthesis and characterization of sulfonated fluorene-containing poly(arylene ether ketone) for proton exchange membrane
Shang, XY; Tian, SH; Kong, LH; Meng, YZ
刊名Journal of membrane science
2005-12-01
卷号266期号:1-2页码:94-101
关键词Polyionomer Polyaromatics Proton exchange membrane Fuel cell Conductivity
ISSN号0376-7388
DOI10.1016/j.memsci.2005.05.014
英文摘要A series of fluorene-containing poly(arylene ether ketone)s were synthesized and sulfonated using chlorosulfonic acid and then were cast into membranes from their solutions. the ionic exchange capacity, sulfonatation degree, water-uptake properties, mechanical properties, thermal stabilities, and oxidative stabilities as well as conductivities were fully investigated. it was found that their conductivities increased continuously with the increasing of temperature up to 100 degrees c at 100% relative humidity. the proton conductivity of the membrane was determined to be close to that of nafion-117 at 100 degrees c under the same testing conditions, together with the comprehensive properties for proton exchange membrane. (c) 2005 elsevier b.v. all rights reserved.
WOS关键词CONDUCTIVE POLYIMIDE ELECTROLYTES ; FUEL-CELL APPLICATIONS ; ACID GROUPS ; POLYMER ; POLYBENZIMIDAZOLE ; POLYETHERETHERKETONE ; POLYSULFONE ; COPOLYMERS ; BLENDS
WOS研究方向Engineering ; Polymer Science
WOS类目Engineering, Chemical ; Polymer Science
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000233067400010
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2377185
专题中国科学院大学
作者单位1.Sun Yat Sen Univ, State Key Lab Optoelect Mat & Techno, Guangzhou 510275, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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GB/T 7714
Shang, XY,Tian, SH,Kong, LH,et al. Synthesis and characterization of sulfonated fluorene-containing poly(arylene ether ketone) for proton exchange membrane[J]. Journal of membrane science,2005,266(1-2):94-101.
APA Shang, XY,Tian, SH,Kong, LH,&Meng, YZ.(2005).Synthesis and characterization of sulfonated fluorene-containing poly(arylene ether ketone) for proton exchange membrane.Journal of membrane science,266(1-2),94-101.
MLA Shang, XY,et al."Synthesis and characterization of sulfonated fluorene-containing poly(arylene ether ketone) for proton exchange membrane".Journal of membrane science 266.1-2(2005):94-101.
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