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	Preparation, characterization and redox chemistry of oxo-centered triruthenium dimers linked by bis(diphenylphosphino)anthracene and -ferrocene
	Chen, JL; Zhang, LY; Shi, LX; Ye, HY; Chen, ZN
刊名	Inorganica chimica acta
	2005-03-01
卷号	358期号:4页码:859-864
关键词	Bis(diphenylphosphino)anthracene Bis(diphenylphosphino)ferrocene Electronic communication P ligand Redox properties Ruthenium
ISSN号	0020-1693
DOI	10.1016/j.ica.2004.10.013
通讯作者	Chen, zn()
英文摘要	Diphosphine-bridged dimers of oxo-centered triruthenium-acetate cluster units, i.e., [{ru3o(oac)(6)(py)(2)}(2)(dppan)](pf6)(2) (2) and [{ru3o(oac)(6)(py)(2)}(2)(dppf)](pf6)(2) (3) were prepared by reaction of 2.3 equivalent [ru3o(oac)(6)(py)(2)(ch3oh)](pf6) with 9,10-bis(diphenylphosphino)anthracene (dppan) or 1,1'-bis(diphenylphosphino)ferrocene (dppf), respectively. apparent redox wave splitting is observed in complex 2, revealing the presence of electronic communication between two triruthenium units mediated through bridging dppan. the complexes were characterized by elemental analysis, ir, uv-vis, p-31 nmr, and es-ms spectroscopies, and cyclic and differential-pulse voltammetry. the crystal structure of complex 3 was determined by x-ray crystallography. (c) 2004 elsevier b.v. all rights reserved.
WOS关键词	INTRAMOLECULAR ELECTRON-TRANSFER ; TRINUCLEAR RUTHENIUM COMPLEX ; VIBRATIONAL TIME-SCALE ; MIXED-VALENCE STATE ; ORGANOMETALLIC COMPLEXES ; REVERSIBLE MULTISTEP ; ISOCYANIDE LIGANDS ; ACETATE CLUSTERS ; METAL-COMPLEXES ; BEHAVIOR
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000227507800001
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2377166
专题	中国科学院大学
通讯作者	Chen, ZN
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Chen, JL,Zhang, LY,Shi, LX,et al. Preparation, characterization and redox chemistry of oxo-centered triruthenium dimers linked by bis(diphenylphosphino)anthracene and -ferrocene[J]. Inorganica chimica acta,2005,358(4):859-864.
APA	Chen, JL,Zhang, LY,Shi, LX,Ye, HY,&Chen, ZN.(2005).Preparation, characterization and redox chemistry of oxo-centered triruthenium dimers linked by bis(diphenylphosphino)anthracene and -ferrocene.Inorganica chimica acta,358(4),859-864.
MLA	Chen, JL,et al."Preparation, characterization and redox chemistry of oxo-centered triruthenium dimers linked by bis(diphenylphosphino)anthracene and -ferrocene".Inorganica chimica acta 358.4(2005):859-864.

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