Effect of regeneration method on activity for simultaneous removal of so2 and no over v2o5/ac catalyst-sorbent | |
Ma, JR; Huang, ZG; Liu, ZY; Guo, SJ | |
刊名 | Chinese journal of catalysis |
2005-06-01 | |
卷号 | 26期号:6页码:463-469 |
关键词 | Vanadium pentoxide Activated carbon Sulfur dioxide Nitric oxide Removal Water-washing Catalyst regeneration Ammonia |
ISSN号 | 0253-9837 |
通讯作者 | Liu, zy() |
英文摘要 | The regeneration of a used v2o5 /ac catalyst-sorbent, which is active for simultaneous removal of so2 and no from flue gas, was studied using different methods. water-washing caused the loss of a considerable amount of v from the catalyst surface and consequently could not rejuvenate the initial activity of the catalyst. thermal regeneration by ar showed better results, but the activity for so2 removal could not be fully recovered due to the presence of residue sulfur and the loss of carbon in the catalyst. reductive regeneration by 5% nh3-95% ar displayed the best results, the so2 removal activity could be completely revived and the no removal activity improved greatly. the results of ir and xps showed that a large amount of nitrogen function groups, nh4+/nh2-, were formed and enhanced the no removal activity. ammonia could also react with the formed so2 to produce ammonium sulfite at the reactor outlet, which simplified the post-treatment process. |
WOS关键词 | LOW-TEMPERATURE ; REDUCTION ; AMMONIA ; GAS ; DESULFURIZATION ; ADSORPTION ; NH3 |
WOS研究方向 | Chemistry ; Engineering |
WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
语种 | 英语 |
出版者 | SCIENCE PRESS |
WOS记录号 | WOS:000230445000009 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2377036 |
专题 | 中国科学院大学 |
通讯作者 | Liu, ZY |
作者单位 | 1.Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, Taiyuan 030001, Shanxi, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, JR,Huang, ZG,Liu, ZY,et al. Effect of regeneration method on activity for simultaneous removal of so2 and no over v2o5/ac catalyst-sorbent[J]. Chinese journal of catalysis,2005,26(6):463-469. |
APA | Ma, JR,Huang, ZG,Liu, ZY,&Guo, SJ.(2005).Effect of regeneration method on activity for simultaneous removal of so2 and no over v2o5/ac catalyst-sorbent.Chinese journal of catalysis,26(6),463-469. |
MLA | Ma, JR,et al."Effect of regeneration method on activity for simultaneous removal of so2 and no over v2o5/ac catalyst-sorbent".Chinese journal of catalysis 26.6(2005):463-469. |
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