Dmap-catalyzed diels-alder reaction of 3-hydroxy-2-pyrone and methyleneindolinones for the synthesis of spirocyclic oxindolesl | |
Zhou, Ming-Qiang1,2; Zhao, Jian-Qiang1,2; You, Yong1,2; Xu, Xiao-Ying1; Zhang, Xiao-Mei1; Yuan, Wei-Cheng1 | |
刊名 | Tetrahedron |
2015-06-10 | |
卷号 | 71期号:23页码:3903-3908 |
关键词 | Diels-alder reaction 3-hydroxy-2-pyrone Methyleneindolinones Spirocyclic oxindoles 4-dimethylaminopyridine |
ISSN号 | 0040-4020 |
DOI | 10.1016/j.tet.2015.04.032 |
通讯作者 | Yuan, wei-cheng(yuanwc@cioc.ac.cn) |
英文摘要 | An efficient diels-alder reaction of 3-hydroxy-2-pyrone with a wide range of methyleneindolinones has been developed by employing 4-dimethylaminopyridine as a catalyst under mild reaction conditions. this process provides a promising method for the construction of structurally diverse spirocyclic oxindoles containing bicyclic lactone motif with moderate diastereoselectivities and good to excellent yields. (c) 2015 elsevier ltd. all rights reserved. |
WOS关键词 | ASYMMETRIC-SYNTHESIS ; HIGHLY EFFICIENT ; STEREOSELECTIVE CONSTRUCTION ; 3-ISOTHIOCYANATO OXINDOLES ; NATURAL-PRODUCTS ; SPIRO COMPOUNDS ; SPIROOXINDOLES ; MICHAEL ; STEREOCENTERS ; 2-PYRONES |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000356125500018 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2376450 |
专题 | 中国科学院大学 |
通讯作者 | Yuan, Wei-Cheng |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Natl Engn Res Ctr Chiral Drugs, Chengdu 610041, Peoples R China 2.Univ Chinese Acad Sci, Being 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, Ming-Qiang,Zhao, Jian-Qiang,You, Yong,et al. Dmap-catalyzed diels-alder reaction of 3-hydroxy-2-pyrone and methyleneindolinones for the synthesis of spirocyclic oxindolesl[J]. Tetrahedron,2015,71(23):3903-3908. |
APA | Zhou, Ming-Qiang,Zhao, Jian-Qiang,You, Yong,Xu, Xiao-Ying,Zhang, Xiao-Mei,&Yuan, Wei-Cheng.(2015).Dmap-catalyzed diels-alder reaction of 3-hydroxy-2-pyrone and methyleneindolinones for the synthesis of spirocyclic oxindolesl.Tetrahedron,71(23),3903-3908. |
MLA | Zhou, Ming-Qiang,et al."Dmap-catalyzed diels-alder reaction of 3-hydroxy-2-pyrone and methyleneindolinones for the synthesis of spirocyclic oxindolesl".Tetrahedron 71.23(2015):3903-3908. |
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