| Synthesis, crystal structure and properties of the strontium vanadate fluoride sr-5(vo4)(3)f | |
| Zhang, Fangyuan1,2,3; Zhang, Fangfang2; Jing, Qun2,3; Pan, Shilie2; Yang, Zhihua2; Jia, Dianzeng1 | |
| 刊名 | Zeitschrift fur anorganische und allgemeine chemie
 |
| 2015-06-01 | |
| 卷号 | 641期号:7页码:1211-1215 |
| 关键词 | Sr-5(vo4)(3)f Vanadate fluoride Synthesis Electronic structure |
| ISSN号 | 0044-2313 |
| DOI | 10.1002/zaac.201500079 |
| 通讯作者 | Zhang, fangfang(ffzhang@ms.xjb.ac.cn) |
| 英文摘要 | The apatite-type strontium vanadate fluoride sr-5(vo4)(3)f was synthesized by standard solid-state reaction method and grown by spontaneous crystallization flux method. it crystallizes in the hexagonal space group p6(3)/m with lattice constants a = 9.988(4) angstrom, c = 7.415(6) angstrom, z = 2. the structure consists of infinite three-dimensional [sr(2)(2)(vo4)(3)](5+) framework with tunnels along the c axis, where sr(1)(2+) and f- ions are filled. functional groups in the structure have been identified by ir spectroscopy and the very high thermal stability up to 1400 degrees c has been identified by tg and dsc analyses. uv/vis/nir diffuse reflectance spectroscopy and first-principle theoretical studies were also carried out to aid the understanding of optical properties and electronic structure. |
| WOS关键词 | ELECTRONIC-STRUCTURE ; MAGNETIC-PROPERTIES ; OPTICAL-PROPERTIES ; APATITE ; GROWTH ; SR |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000356722400004 |
| 内容类型 | 期刊论文 |
| URI标识 | http://www.corc.org.cn/handle/1471x/2376396 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhang, Fangfang |
| 作者单位 | 1.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China 2.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Fangyuan,Zhang, Fangfang,Jing, Qun,et al. Synthesis, crystal structure and properties of the strontium vanadate fluoride sr-5(vo4)(3)f[J]. Zeitschrift fur anorganische und allgemeine chemie,2015,641(7):1211-1215. |
| APA | Zhang, Fangyuan,Zhang, Fangfang,Jing, Qun,Pan, Shilie,Yang, Zhihua,&Jia, Dianzeng.(2015).Synthesis, crystal structure and properties of the strontium vanadate fluoride sr-5(vo4)(3)f.Zeitschrift fur anorganische und allgemeine chemie,641(7),1211-1215. |
| MLA | Zhang, Fangyuan,et al."Synthesis, crystal structure and properties of the strontium vanadate fluoride sr-5(vo4)(3)f".Zeitschrift fur anorganische und allgemeine chemie 641.7(2015):1211-1215. |
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