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Fes2@c nanowires derived from organic-inorganic hybrid nanowires for high-rate and long-life lithium-ion batteries
Zhang, Feifei1,2; Wang, Chunli1,2; Huang, Gang1,2; Yin, Dongming1,2; Wang, Limin1,3
刊名Journal of power sources
2016-10-01
卷号328页码:56-64
关键词1d nanomaterials Fes2@c nanowires Carbon encapsulation Lithium-ion batteries
ISSN号0378-7753
DOI10.1016/j.jpowsour.2016.07.117
通讯作者Wang, limin(lmwang@ciac.ac.cn)
英文摘要One-dimensional (1d) porous fes2@c nanowires as a high cathode material for lithium-ion batteries (libs) are synthesized on a large-scale from an organic-inorganic hybrid nanowire precursor. the fes2@c nanowires not only provide a continuous and fast electron transport pathway, favorable diffusion kinetics, but also provide the protection buffer the volume expansion and effectively prevent the poly sulfides from dissolving in the electrolyte during cycling. attributing to the synergistic advantages of both 1d porous nanostructure and the encapsulation of thin amorphous carbon layers, the fes2@c nanowires exhibit remarkable lithium storage performance with a high specific capacity of 889 ma h g(-1) at 0.1 a g(-1) and 521 ma h g(-1) at 10 a g(-1). moreover, a discharge energy density of 1225 wh kg(-1) is obtained at 2 a g(-1) and remains as high as 637 wh kg(-1) after 1000 cycles, which is even higher than the licoo2 cathode. the results demonstrate that the potential for applications in libs with high power density and long cycling life. (c) 2016 elsevier b.v. all rights reserved.
WOS关键词REDUCED GRAPHENE OXIDE ; PYRITE FES2 NANOWIRES ; SULFUR BATTERIES ; STORAGE PERFORMANCE ; CATHODE MATERIAL ; HIGH-CAPACITY ; COMPOSITE ; CARBON ; NANOSTRUCTURES ; MICROSPHERES
WOS研究方向Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
WOS类目Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000383293400007
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2376303
专题中国科学院大学
通讯作者Wang, Limin
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Changzhou Inst Energy Storage Mat & Devices, Changzhou 213000, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Feifei,Wang, Chunli,Huang, Gang,et al. Fes2@c nanowires derived from organic-inorganic hybrid nanowires for high-rate and long-life lithium-ion batteries[J]. Journal of power sources,2016,328:56-64.
APA Zhang, Feifei,Wang, Chunli,Huang, Gang,Yin, Dongming,&Wang, Limin.(2016).Fes2@c nanowires derived from organic-inorganic hybrid nanowires for high-rate and long-life lithium-ion batteries.Journal of power sources,328,56-64.
MLA Zhang, Feifei,et al."Fes2@c nanowires derived from organic-inorganic hybrid nanowires for high-rate and long-life lithium-ion batteries".Journal of power sources 328(2016):56-64.
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