| Visualizing the dynamics of temperature- and solvent-responsive soft crystals | |
| Pang, Jiandong1,2; Liu, Caiping1; Huang, Yougui3; Wu, Mingyan1; Jiang, Feilong1; Yuan, Daqiang1; Hu, Falu1,2; Su, Kongzhao1; Liu, Guoliang1,2; Hong, Maochun1 | |
| 刊名 | Angewandte chemie-international edition
 |
| 2016-06-20 | |
| 卷号 | 55期号:26页码:7478-7482 |
| 关键词 | Metal-organic frameworks Solvent responsive Stimuli-responsive materials Temperature responsive X-ray snapshot analyses |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201603030 |
| 通讯作者 | Wu, mingyan(wumy@fjirsm.ac.cn) ; Yuan, daqiang(ydq@fjirsm.ac.cn) |
| 英文摘要 | We demonstrate that three flexible mofs termed fji-h11-r (fji-h=hong's group in fujian institute of research on the structure of matter, r=me, et, pr-i) can reversibly respond to temperature and solvents via structural transformations, which can be visualized by in situ single-crystal x-ray snapshot analyses. fji-h11-r exhibit colossal anisotropic thermal expansion, with a record-high uniaxial positive thermal-expansion coefficient of 653.2 x 10(-6) k-1 observed in fji-h11-me. additionally, large c-axial shrinkage of 32.4% is also observed during desolvation. the stimuli-responsive mechanism reveals the structural evolutions are related to the rotations and deformations of the organic linkers. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; NEGATIVE THERMAL-EXPANSION ; COORDINATION FRAMEWORKS ; POTENTIAL APPLICATIONS ; SELECTIVE SORPTION ; POROUS CRYSTALS ; GUEST ; TRANSITION ; COMPRESSIBILITY ; LUMINESCENCE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000383077400029 |
| 内容类型 | 期刊论文 |
| URI标识 | http://www.corc.org.cn/handle/1471x/2376249 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Mingyan; Yuan, Daqiang |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8190395, Japan |
| 推荐引用方式 GB/T 7714 | Pang, Jiandong,Liu, Caiping,Huang, Yougui,et al. Visualizing the dynamics of temperature- and solvent-responsive soft crystals[J]. Angewandte chemie-international edition,2016,55(26):7478-7482. |
| APA | Pang, Jiandong.,Liu, Caiping.,Huang, Yougui.,Wu, Mingyan.,Jiang, Feilong.,...&Hong, Maochun.(2016).Visualizing the dynamics of temperature- and solvent-responsive soft crystals.Angewandte chemie-international edition,55(26),7478-7482. |
| MLA | Pang, Jiandong,et al."Visualizing the dynamics of temperature- and solvent-responsive soft crystals".Angewandte chemie-international edition 55.26(2016):7478-7482. |
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