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	Transition-metal-free stereospecific cross-coupling with alkenylboronic acids as nucleophiles
	Li, Chengxi; Zhang, Yuanyuan; Sun, Qi; Gu, Tongnian; Peng, Henian; Tang, Wenjun
刊名	Journal of the american chemical society
	2016-08-31
卷号	138期号:34页码:10774-10777
ISSN号	0002-7863
DOI	10.1021/jacs.6b06285
通讯作者	Tang, wenjun(tangwenjun@sioc.ac.cn)
英文摘要	We herein report a transition-metal-free cross-coupling between secondary alkyl halides/mesylates and aryl/alkenylboronic acid, providing expedited access to a series of nonchiral/chiral coupling products in moderate to good yields. stereospecific s(n)2-type coupling is developed for the first time with alkenylboronic adds as pure nucleophiles, offering an attractive alternative to the stereospecific transition-metal-catalyzed c(sp(2))-c(sp(3)) cross-coupling.
WOS关键词	TERTIARY BORONIC ESTERS ; ALPHA-AMINO-ACIDS ; NEGISHI ARYLATIONS ; ARYLBORONIC ACIDS ; ALLYLIC BROMIDES ; NICKEL CATALYSIS ; ARYL CHLORIDES ; SECONDARY ; ELECTROPHILES ; LIGAND
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000382513300015
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2375677
专题	中国科学院大学
通讯作者	Tang, Wenjun
作者单位	Univ Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, 345 Ling Ling Rd, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Li, Chengxi,Zhang, Yuanyuan,Sun, Qi,et al. Transition-metal-free stereospecific cross-coupling with alkenylboronic acids as nucleophiles[J]. Journal of the american chemical society,2016,138(34):10774-10777.
APA	Li, Chengxi,Zhang, Yuanyuan,Sun, Qi,Gu, Tongnian,Peng, Henian,&Tang, Wenjun.(2016).Transition-metal-free stereospecific cross-coupling with alkenylboronic acids as nucleophiles.Journal of the american chemical society,138(34),10774-10777.
MLA	Li, Chengxi,et al."Transition-metal-free stereospecific cross-coupling with alkenylboronic acids as nucleophiles".Journal of the american chemical society 138.34(2016):10774-10777.

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