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Highly efficient beta-sic-supported 0.5% rh-based catalyst for co hydrogenation to c-2 oxygenates
Chen, Weimiao1; Ding, Yunjie1,2; Xue, Fei1,3; Song, Xiangen1; Ning, Lili1
刊名Catalysis communications
2016-10-05
卷号85页码:44-47
关键词Beta-sic Rh-based catalyst Co hydrogenation C-2 oxygenates Low rh loading
ISSN号1566-7367
DOI10.1016/j.catcom.2016.07.016
通讯作者Ding, yunjie(dyj@dicp.ac.cn)
英文摘要Beta-sic was used as a support for a 0.5% rh-based catalyst for co hydrogenation to c-2 oxygenates for the first time. the beta-sic was acid etched and/or calcined at high temperature before use. the results show that the pretreatments had little effect on the textural and crystal properties of sic, but calcination markedly increased the number of surface oxygen-containing groups. the pretreatment significantly increased the catalytic activities of sic-supported rh-mn-li/sic catalysts in co hydrogenation. an rh efficiency of 97.2 g/g-rh/h was achieved, the highest value reported in the literature to date. possible reasons for this enhancement are suggested. (c) 2016 elsevier b.v. all rights reserved.
WOS关键词FISCHER-TROPSCH SYNTHESIS ; ETHANOL-PRODUCTION ; SILICON-CARBIDE ; PERFORMANCE ; PROMOTION ; OXIDATION ; BEHAVIOR ; SURFACE ; SYNGAS ; NI
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000382594800011
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2375476
专题中国科学院大学
通讯作者Ding, Yunjie
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Chen, Weimiao,Ding, Yunjie,Xue, Fei,et al. Highly efficient beta-sic-supported 0.5% rh-based catalyst for co hydrogenation to c-2 oxygenates[J]. Catalysis communications,2016,85:44-47.
APA Chen, Weimiao,Ding, Yunjie,Xue, Fei,Song, Xiangen,&Ning, Lili.(2016).Highly efficient beta-sic-supported 0.5% rh-based catalyst for co hydrogenation to c-2 oxygenates.Catalysis communications,85,44-47.
MLA Chen, Weimiao,et al."Highly efficient beta-sic-supported 0.5% rh-based catalyst for co hydrogenation to c-2 oxygenates".Catalysis communications 85(2016):44-47.
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