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	Tetrazole-viologen-based flexible microporous metal-organic framework with high co2 selective uptake
	Zhao, Ya-Ping1,2; Li, Yan3; Cui, Cai-Yan1,2; Xiao, Yu1,2; Li, Rong1,2; Wang, Shuai-Hua1; Zheng, Fa-Kun1; Guo, Guo-Cong1
刊名	Inorganic chemistry
	2016-08-01
卷号	55期号:15页码:7335-7340
ISSN号	0020-1669
DOI	10.1021/acs.inorgchem.6b00320
通讯作者	Wang, shuai-hua(shwang@fjirsm.ac.cn) ; Zheng, fa-kun(zfk@fjirsm.ac.cn)
英文摘要	A flexible, metal-organic framework (fmof) with functionalized pots was hydrothermally: synthesized to improve co, affinity and selectivity. the obtained fmof exhibits a reversible shrinking and swelling framework transformation, which is triggered by the adsorption of co2 rather than by the adsorption of in, and ch4. at ambient temperature and an atmospheric pressure, this fmof shows not only a high co2 uptake (98 cm(3) g(-1), 19.3 wt %) but also a good calculated adsorption selectivity for co, over both ch4 and n-2 (co2/ch4 50:50 v/v: 28.6:1, co2/n-2 15:85 v/v: 210.4:1 calculated by ideal adsorbed solution theory), indicating potential applications in the purification of natural gas and industrial flue gas
WOS关键词	POROUS COORDINATION POLYMERS ; GAS-ADSORPTION PROPERTIES ; CARBON-DIOXIDE CAPTURE ; SEPARATION ; EFFICIENT ; CO2/CH4 ; SITES ; 1,2-BIS(4-PYRIDYL)HYDRAZINE ; THERMODYNAMICS ; MOLECULES
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000380864900025
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2375394
专题	中国科学院大学
通讯作者	Wang, Shuai-Hua; Zheng, Fa-Kun
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.East China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Ya-Ping,Li, Yan,Cui, Cai-Yan,et al. Tetrazole-viologen-based flexible microporous metal-organic framework with high co2 selective uptake[J]. Inorganic chemistry,2016,55(15):7335-7340.
APA	Zhao, Ya-Ping.,Li, Yan.,Cui, Cai-Yan.,Xiao, Yu.,Li, Rong.,...&Guo, Guo-Cong.(2016).Tetrazole-viologen-based flexible microporous metal-organic framework with high co2 selective uptake.Inorganic chemistry,55(15),7335-7340.
MLA	Zhao, Ya-Ping,et al."Tetrazole-viologen-based flexible microporous metal-organic framework with high co2 selective uptake".Inorganic chemistry 55.15(2016):7335-7340.

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