Two near-infrared emissive lanthanide-based metal-organic complexes constructed from efficient energy transfer ligand | |
Zou Shu-Zhi1; Du Shao-Wu1 | |
刊名 | Chinese journal of structural chemistry |
2016-07-01 | |
卷号 | 35期号:7页码:1077-1084 |
关键词 | Synthesis Crystal structure Near-infrared material Lanthanide-based complexes |
ISSN号 | 0254-5861 |
DOI | 10.14102/j.cnki.0254-5861.2011-0709 |
通讯作者 | Du shao-wu(swdu@fjirsm.ac.cn) |
英文摘要 | Utilizing two polycarboxylic acids as primary ligands and 1,10-phenan-throlion as an auxiliary ligand in the existence of lanthanide nitrates, two lanthanide-based complexes formulated as [nd-4(2,6-pydcoh)(6)(phen)(4)(h2o)(2)](h2o)(2) (1) and [yb-2(mbdc) 3(phen)(2)] n (2) (2,6-h(2)pydcoh = 4-hydroxypyridine-2,6-dicarboxylic acid, m-h2bdc = isophthalic acid, phen = 1,10-phenanthroline) have been solvothermally synthesized. they have been fully characterized by satisfactory elemental analysis, ft-ir spectra, tga and single-crystal x-ray diffraction. single-crystal x-ray diffraction study reveals that 1 has a zero-dimensional structure and 2 exhibits a rare cds topological net structure. compounds 1 and 2 exhibit strong characteristic emissions of nd(iii) and yb(iii) ions in the near-infrared (nir) region. |
WOS关键词 | COORDINATION POLYMERS ; MAGNETIC-PROPERTIES ; LUMINESCENT ; FRAMEWORKS ; 1,10-PHENANTHROLINE ; IONS ; ACID ; PHOTOLUMINESCENCE |
WOS研究方向 | Chemistry ; Crystallography |
WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
语种 | 英语 |
出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
WOS记录号 | WOS:000385766200012 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2374891 |
专题 | 中国科学院大学 |
通讯作者 | Du Shao-Wu |
作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zou Shu-Zhi,Du Shao-Wu. Two near-infrared emissive lanthanide-based metal-organic complexes constructed from efficient energy transfer ligand[J]. Chinese journal of structural chemistry,2016,35(7):1077-1084. |
APA | Zou Shu-Zhi,&Du Shao-Wu.(2016).Two near-infrared emissive lanthanide-based metal-organic complexes constructed from efficient energy transfer ligand.Chinese journal of structural chemistry,35(7),1077-1084. |
MLA | Zou Shu-Zhi,et al."Two near-infrared emissive lanthanide-based metal-organic complexes constructed from efficient energy transfer ligand".Chinese journal of structural chemistry 35.7(2016):1077-1084. |
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