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	Catalytic conversion of glucose into alkanediols over nickel-based catalysts: a mechanism study
	Tan, Zhichao1,2; Miao, Gai1; Liu, Chang1; Luo, Hu1; Bao, Liwei1,2; Kong, Lingzhao1; Sun, Yuhan1,3
刊名	Rsc advances
	2016
卷号	6期号:67页码:62747-62753
ISSN号	2046-2069
DOI	10.1039/c6ra14738k
通讯作者	Kong, lingzhao(konglz@sari.ac.cn) ; Sun, yuhan(sunyh@sari.ac.cn)
英文摘要	The conversion of isotope-labeled glucose (d-1-c-13-glucose) into alkanediols was carried out in a batch reactor over a ni-mgo-zno catalyst to reveal the c-c cleavage mechanisms. the unique role of the mgo-zno support was highlighted by c-13 nmr and gc-ms analysis qualitatively and the mgo-zno favored isomerization of glucose to fructose. c-13 nmr, gc-ms and hplc analysis demonstrated that the cl position of ethylene glycol, the cl and c3 positions of 1,2-propanedioe and the cl position of glycerin were labeled with c-13, which is attributed to a c-c cleavage at d-1-c-13-glucose's corresponding positions through retro-a[doe condensation. a hydrogenoeysis followed by hydrogenation pathway was proposed for glucose converted into alkanediols at 493 k with 6.0 mpa of h2 pressure over ni based catalysts.
WOS关键词	ETHYLENE-GLYCOL ; SUPERCRITICAL WATER ; SELECTIVE CONVERSION ; PROPYLENE-GLYCOL ; HYDROGENOLYSIS ; CELLULOSE ; SORBITOL ; KINETICS ; BIOMASS ; DECOMPOSITION
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000379678200085
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2374722
专题	中国科学院大学
通讯作者	Kong, Lingzhao; Sun, Yuhan
作者单位	1.Chinese Acad Sci, Shanghai Adv Res Inst, CAS Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
推荐引用方式 GB/T 7714	Tan, Zhichao,Miao, Gai,Liu, Chang,et al. Catalytic conversion of glucose into alkanediols over nickel-based catalysts: a mechanism study[J]. Rsc advances,2016,6(67):62747-62753.
APA	Tan, Zhichao.,Miao, Gai.,Liu, Chang.,Luo, Hu.,Bao, Liwei.,...&Sun, Yuhan.(2016).Catalytic conversion of glucose into alkanediols over nickel-based catalysts: a mechanism study.Rsc advances,6(67),62747-62753.
MLA	Tan, Zhichao,et al."Catalytic conversion of glucose into alkanediols over nickel-based catalysts: a mechanism study".Rsc advances 6.67(2016):62747-62753.

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