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	Synthesis of two-dimensional microporous carbonaceous polymer nanosheets and their application as high-performance co2 capture sorbent
	Zhang, Miao1,2; Liu, Lin1; He, Teng1; Wu, Guotao1; Chen, Ping1
刊名	Chemistry-an asian journal
	2016-06-21
卷号	11期号:12页码:1849-1855
关键词	2d carbonaceous polymer nanosheets Carbon dioxide capture Ionothermal method Microporous materials Polymers
ISSN号	1861-4728
DOI	10.1002/asia.201600396
通讯作者	Liu, lin(liulin@dicp.ac.cn) ; Chen, ping(pchen@dicp.ac.cn)
英文摘要	The synthesis of two-dimensional (2d) polymer nanosheets with a well-defined microporous structure remains challenging in materials science. here, a new kind of 2d microporous carbonaceous polymer nanosheets was synthesized through polymerization of a very low concentration of 1,4-dicyanobenzene in molten zinc chloride at 400-500 degrees c. this type of nanosheets has a thickness in the range of 3-20nm, well-defined microporosity, a high surface area (approximate to 537m(2)g(-1)), and a large micropore volume (approximate to 0.45cm(3)g(-1)). the microporous carbonaceous polymer nanosheets exhibit superior co2 sorption capability (8.14wt% at 298k and 1bar) and a relatively high co2 selectivity toward n-2 (25.6). starting from different aromatic nitrile monomers, a variety of 2d carbonaceous polymer nanosheets can be obtained showing a certain universality of the ionothermal method reported herein.
WOS关键词	COVALENT ORGANIC FRAMEWORKS ; TRIAZINE-BASED FRAMEWORKS ; ON-SURFACE SYNTHESIS ; IONOTHERMAL SYNTHESIS ; DIOXIDE CAPTURE ; THIN-FILMS ; AIR/WATER INTERFACE ; LARGE-AREA ; GRAPHENE ; CAPACITY
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000379519400016
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2374692
专题	中国科学院大学
通讯作者	Liu, Lin; Chen, Ping
作者单位	1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Miao,Liu, Lin,He, Teng,et al. Synthesis of two-dimensional microporous carbonaceous polymer nanosheets and their application as high-performance co2 capture sorbent[J]. Chemistry-an asian journal,2016,11(12):1849-1855.
APA	Zhang, Miao,Liu, Lin,He, Teng,Wu, Guotao,&Chen, Ping.(2016).Synthesis of two-dimensional microporous carbonaceous polymer nanosheets and their application as high-performance co2 capture sorbent.Chemistry-an asian journal,11(12),1849-1855.
MLA	Zhang, Miao,et al."Synthesis of two-dimensional microporous carbonaceous polymer nanosheets and their application as high-performance co2 capture sorbent".Chemistry-an asian journal 11.12(2016):1849-1855.

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