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	Investigation on the structure and the conductivity of plasticized polymer electrolytes
	WANG, CH; LIU, QG; CAO, QJ; MENG, QG; YANG, LL
刊名	Solid state ionics
	1992-07-01
卷号	53页码:1106-1110
ISSN号	0167-2738
英文摘要	Electrical properties of polymer electrolytes depend on the structure of polymer matrix. it was reported that transportation of carries in polymer electrolytes was correlated with the segment movement of the amorphous phase. dynamic property of amorphous phase and the crystallinity of electrolyte would effect the conductivity of polymer electrolytes. the properties of peo-licf3so3 modified with additives were investigated by conductivity measurement, dsc and h-1-, f-19-nmr experiments. it was found that additives would increase the content of amorphous phase and salt concentration in amorphous phase, and improve the dynamic property of amorphous phase. the spin-spin relaxation time for the polymer matrix is also increased. it was indicated that the glass transition temperature of modified electrolytes was decreased from -21-degrees-c for typical peo-licf3so3 electrolytes to about -48-degrees-c. these improvements result in the increase of the conductivity.
WOS关键词	BATTERIES
WOS研究方向	Chemistry ; Physics
WOS类目	Chemistry, Physical ; Physics, Condensed Matter
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:A1992JP97200055
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2373679
专题	物理研究所
作者单位	1.ACAD SINICA, INST PHYS, BEIJING 100080, PEOPLES R CHINA 2.BEIJING RES INST CHEM IND, DEPT POLYMER MAT, BEIJING 100013, PEOPLES R CHINA
推荐引用方式 GB/T 7714	WANG, CH,LIU, QG,CAO, QJ,et al. Investigation on the structure and the conductivity of plasticized polymer electrolytes[J]. Solid state ionics,1992,53:1106-1110.
APA	WANG, CH,LIU, QG,CAO, QJ,MENG, QG,&YANG, LL.(1992).Investigation on the structure and the conductivity of plasticized polymer electrolytes.Solid state ionics,53,1106-1110.
MLA	WANG, CH,et al."Investigation on the structure and the conductivity of plasticized polymer electrolytes".Solid state ionics 53(1992):1106-1110.

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