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	Enantiodivergent desymmetrization in the rhodium( iii)-catalyzed annulation of sulfoximines with diazo compounds
	Shen, Bingxue1,2; Wan, Boshun1; Li, Xingwei1,3
刊名	Angewandte chemie-international edition
	2018-11-19
卷号	57期号:47页码:15534-15538
关键词	Asymmetric c-h activation Desymmetrization Enantiodivergence Rhodium Sulfoximes
ISSN号	1433-7851
DOI	10.1002/anie.201810472
通讯作者	Li, xingwei(xwli@dicp.ac.cn)
英文摘要	Rh-iii- and ir-iii-catalyzed asymmetric c-h functionalization reactions of arenes have relied on the employment of chiral rh-iii/ir-iii cyclopentadienyl catalysts, the introduction of chiral carboxylic acids to achiral cp*rhx2 catalysts, and the integration of both strategies. despite considerable progress, each reaction only provided a specific configuration of the enantioenriched product when using a particular chiral catalyst. reported in this work is the enantiodivergent coupling of sulfoximines with various diazo compounds by rh-iii-catalyzed desymmetrizing annulation. the enantiodivergence was enabled by a judicious choice of achiral carboxylic acids, and the enantioselectivity correlates with the steric bias of the carboxylic acid and the sulfoximine.
WOS关键词	C-H ACTIVATION ; N BOND ; ASYMMETRIC-SYNTHESIS ; 2+2+2 CYCLOADDITION ; FUNCTIONALIZATION ; LIGANDS ; COMBINATION ; CATALYSIS ; RH
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000453344500041
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2373009
专题	大连化学物理研究所
通讯作者	Li, Xingwei
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Shaanxi Normal Univ SNNU, Sch Chem & Chem Engn, Xian 710062, Shaanxi, Peoples R China
推荐引用方式 GB/T 7714	Shen, Bingxue,Wan, Boshun,Li, Xingwei. Enantiodivergent desymmetrization in the rhodium( iii)-catalyzed annulation of sulfoximines with diazo compounds[J]. Angewandte chemie-international edition,2018,57(47):15534-15538.
APA	Shen, Bingxue,Wan, Boshun,&Li, Xingwei.(2018).Enantiodivergent desymmetrization in the rhodium( iii)-catalyzed annulation of sulfoximines with diazo compounds.Angewandte chemie-international edition,57(47),15534-15538.
MLA	Shen, Bingxue,et al."Enantiodivergent desymmetrization in the rhodium( iii)-catalyzed annulation of sulfoximines with diazo compounds".Angewandte chemie-international edition 57.47(2018):15534-15538.

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