| Nife hydroxide lattice tensile strain: enhancement of adsorption of oxygenated intermediates for efficient water oxidation catalysis | |
| Zhou, Daojin1,2; Wang, Shiyuan1,3; Jia, Yin1,3; Xiong, Xuya1; Yang, Hongbin2,4; Liu, Song5; Tang, Jialun6; Zhang, Junming2; Liu, Dong2; Zheng, Lirong7 | |
| 刊名 | Angewandte chemie-international edition
 |
| 2019-01-14 | |
| 卷号 | 58期号:3页码:736-740 |
| 关键词 | Ball-milling Nife catalysts Oxygen evolution Tensile strain |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201809689 |
| 通讯作者 | Kuang, yun(kuangyun@mail.buct.edu.cn) ; Sun, xiaoming(sunxm@mail.buct.edu.cn) ; Liu, bin(liubin@ntu.edu.sg) |
| 英文摘要 | The binding strength of reactive intermediates with catalytically active sites plays a crucial role in governing catalytic performance of electrocatalysts. nife hydroxide offers efficient oxygen evolution reaction (oer) catalysis in alkaline electrolyte, however weak binding of oxygenated intermediates on nife hydroxide still badly limits its catalytic activity. now, a facile ball-milling method was developed to enhance binding strength of nife hydroxide to oxygenated intermediates via generating tensile strain, which reduced the anti-bonding filling states in the d orbital and thus facilitated oxygenated intermediates adsorption. the nife hydroxide with tensile strain increasing after ball-milling exhibits an oer onset potential as low as 1.44 v (vs. reversible hydrogen electrode) and requires only a 270 mv overpotential to reach a water oxidation current density of 10 ma cm(-2). |
| WOS关键词 | EVOLUTION REACTION ; OXIDE CATALYSTS ; METAL-OXIDES ; FE-SITES ; REDUCTION ; ELECTROCHEMISTRY ; ELECTROCATALYSTS ; IDENTIFICATION ; NANOPARTICLES ; REACTIVITY |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000455033700011 |
| 内容类型 | 期刊论文 |
| URI标识 | http://www.corc.org.cn/handle/1471x/2372946 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Kuang, Yun; Sun, Xiaoming; Liu, Bin |
| 作者单位 | 1.Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore 3.Beijing Univ Chem Technol, Coll Energy, Beijing 100029, Peoples R China 4.Suzhou Univ Sci & Technol, Inst Mat Sci & Devices, Suzhou 215009, Peoples R China 5.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 6.Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Nanophoton & Ultrafine Optoelect, Beijing 100029, Peoples R China 7.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Daojin,Wang, Shiyuan,Jia, Yin,et al. Nife hydroxide lattice tensile strain: enhancement of adsorption of oxygenated intermediates for efficient water oxidation catalysis[J]. Angewandte chemie-international edition,2019,58(3):736-740. |
| APA | Zhou, Daojin.,Wang, Shiyuan.,Jia, Yin.,Xiong, Xuya.,Yang, Hongbin.,...&Liu, Bin.(2019).Nife hydroxide lattice tensile strain: enhancement of adsorption of oxygenated intermediates for efficient water oxidation catalysis.Angewandte chemie-international edition,58(3),736-740. |
| MLA | Zhou, Daojin,et al."Nife hydroxide lattice tensile strain: enhancement of adsorption of oxygenated intermediates for efficient water oxidation catalysis".Angewandte chemie-international edition 58.3(2019):736-740. |
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