Superior Au-adsorption performance of aminothiourea-modified waste cellulosic biomass | |
Wang, Fu-chun1; Zhao, Jun-mei2; Wang, Wan-kun1; Liu, Hui-zhou2 | |
刊名 | JOURNAL OF CENTRAL SOUTH UNIVERSITY |
2018-12-01 | |
卷号 | 25期号:12页码:2992-3003 |
关键词 | Adsorption Reduction-deposition Waste Cellulosic Biomass Aminothiourea Gold Nanoparticles |
ISSN号 | 2095-2899 |
DOI | 10.1007/s11771-018-3969-3 |
英文摘要 | Waste cellulosic biomass obtains various applications due to low-cost and eco-benign characteristics. A general strategy is proposed for waste cellulosic biomass to be modified with dialdehyde functional groups as intermediates through periodate partial oxidation. Finally, aminothiourea-modified waste cellulosic biomass can be prepared through Schiff reaction. Waste corn stalk, cotton and paper as typical precursors, were used to prepare cellulosic biomass, abbreviated as AT-S, AT-C and AT-P, respectively, and their adsorption behaviors of Au(III) from the hydrochloric acid medium were investigated. The pseudo-second kinetics equation as well as the Langmuir isotherm equation can be used to depict the adsorption process, and the maximum adsorption capacities of Au(III) are 21.4, 19.0 and 3.28 mol/kg for AT-S, AT-C and AT-P at 298 K, respectively. The adsorption capacities of Au(III) on aminothiourea modified corn stalk (AT-S) is almost 357 times greater than that of raw corn stalk. To the best of our knowledge, AT-S has the highest adsorption capacity towards Au(III). AT-S also displays a superior separation selectivity towards Au(III) in the presence of Cu(II), Ni(II), Co(II), Pt(VI), Pd(II) and Rh(III). Furthermore, the characterization analysis of XRD, TG, SEM, TEM and FTIR confirms that AuCl4- has been reduced to elemental Au nanoparticles and deposit onto the surface of the biomass. It shows a prospect for waste corn stalk to be used to adsorb Au(III) from liquid phase and the possible fabrication of gold nanoparticles by a general adsorption process without any reductant. |
资助项目 | National Natural Science Foundation of China[51504073] ; National Natural Science Foundation of China[51404081] ; National Natural Science Foundation of China[51672275] ; National Key Technology Research and Development Program of the Ministry of Science and Technology, China[2012CBA01202] ; Research Program of the Education Department of Guizhou Province, China[QianJiaoKeHe KY[2015] 433] ; Research Program of Talented Scholars of Guizhou Institute of Technology, China[XJG20141104] |
WOS关键词 | Enhanced Adsorption ; Selective Recovery ; Gold Recovery ; Biosorption ; Gold(Iii) ; Au(Iii) ; Silver(i) ; Metals ; Cd(Ii) ; Tannin |
WOS研究方向 | Metallurgy & Metallurgical Engineering |
语种 | 英语 |
出版者 | JOURNAL OF CENTRAL SOUTH UNIV |
WOS记录号 | WOS:000455260900013 |
资助机构 | National Natural Science Foundation of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology, China ; Research Program of the Education Department of Guizhou Province, China ; Research Program of Talented Scholars of Guizhou Institute of Technology, China |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/27737] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Zhao, Jun-mei |
作者单位 | 1.Guizhou Inst Technol, Sch Mat & Met Engn, Guiyang 550003, Guizhou, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Fu-chun,Zhao, Jun-mei,Wang, Wan-kun,et al. Superior Au-adsorption performance of aminothiourea-modified waste cellulosic biomass[J]. JOURNAL OF CENTRAL SOUTH UNIVERSITY,2018,25(12):2992-3003. |
APA | Wang, Fu-chun,Zhao, Jun-mei,Wang, Wan-kun,&Liu, Hui-zhou.(2018).Superior Au-adsorption performance of aminothiourea-modified waste cellulosic biomass.JOURNAL OF CENTRAL SOUTH UNIVERSITY,25(12),2992-3003. |
MLA | Wang, Fu-chun,et al."Superior Au-adsorption performance of aminothiourea-modified waste cellulosic biomass".JOURNAL OF CENTRAL SOUTH UNIVERSITY 25.12(2018):2992-3003. |
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